Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W2095699355', 'doi': 'https://doi.org/10.1002/anie.201000762', 'title': 'Selective Oxidation of Glycerol under Acidic Conditions Using Gold Catalysts', 'display_name': 'Selective Oxidation of Glycerol under Acidic Conditions Using Gold Catalysts', 'publication_year': 2010, 'publication_date': '2010-05-11', 'ids': {'openalex': 'https://openalex.org/W2095699355', 'doi': 'https://doi.org/10.1002/anie.201000762', 'mag': '2095699355', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/20461742'}, 'language': 'en', 'primary_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1002/anie.201000762', 'pdf_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201000762', 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': True, 'oa_status': 'bronze', 'oa_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201000762', 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5011812717', 'display_name': 'Alberto Villa', 'orcid': 'https://orcid.org/0000-0001-8656-6256'}, 'institutions': [{'id': 'https://openalex.org/I189158943', 'display_name': 'University of Milan', 'ror': 'https://ror.org/00wjc7c48', 'country_code': 'IT', 'type': 'education', 'lineage': ['https://openalex.org/I189158943']}], 'countries': ['IT'], 'is_corresponding': False, 'raw_author_name': 'Alberto Villa', 'raw_affiliation_strings': ['Department of Inorganic Chemistry L.\u2005Malatesta, Università degli Studi di Milano via Venezian 21, 20133 Milano (Italy), Fax: (+39)\u200902-503-14405'], 'affiliations': [{'raw_affiliation_string': 'Department of Inorganic Chemistry L.\u2005Malatesta, Università degli Studi di Milano via Venezian 21, 20133 Milano (Italy), Fax: (+39)\u200902-503-14405', 'institution_ids': ['https://openalex.org/I189158943']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5039183578', 'display_name': 'Gabriel M. Veith', 'orcid': 'https://orcid.org/0000-0002-5186-4461'}, 'institutions': [{'id': 'https://openalex.org/I1289243028', 'display_name': 'Oak Ridge National Laboratory', 'ror': 'https://ror.org/01qz5mb56', 'country_code': 'US', 'type': 'facility', 'lineage': ['https://openalex.org/I1289243028', 'https://openalex.org/I1330989302', 'https://openalex.org/I39565521', 'https://openalex.org/I4210159294']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Gabriel\u2005M. Veith', 'raw_affiliation_strings': ['Materials, Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA'], 'affiliations': [{'raw_affiliation_string': 'Materials, Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA', 'institution_ids': ['https://openalex.org/I1289243028']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5002017862', 'display_name': 'Laura Prati', 'orcid': 'https://orcid.org/0000-0002-8227-9505'}, 'institutions': [{'id': 'https://openalex.org/I189158943', 'display_name': 'University of Milan', 'ror': 'https://ror.org/00wjc7c48', 'country_code': 'IT', 'type': 'education', 'lineage': ['https://openalex.org/I189158943']}], 'countries': ['IT'], 'is_corresponding': False, 'raw_author_name': 'Laura Prati', 'raw_affiliation_strings': ['Department of Inorganic Chemistry L.\u2005Malatesta, Università degli Studi di Milano via Venezian 21, 20133 Milano (Italy), Fax: (+39)\u200902-503-14405'], 'affiliations': [{'raw_affiliation_string': 'Department of Inorganic Chemistry L.\u2005Malatesta, Università degli Studi di Milano via Venezian 21, 20133 Milano (Italy), Fax: (+39)\u200902-503-14405', 'institution_ids': ['https://openalex.org/I189158943']}]}], 'institution_assertions': [], 'countries_distinct_count': 2, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 5250, 'currency': 'USD', 'value_usd': 5250, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 16.713, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 233, 'citation_normalized_percentile': {'value': 0.99997, 'is_in_top_1_percent': True, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 98, 'max': 99}, 'biblio': {'volume': '49', 'issue': '26', 'first_page': '4499', 'last_page': '4502'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11009', 'display_name': 'Catalysis for Biomass Conversion', 'score': 0.9998, 'subfield': {'id': 'https://openalex.org/subfields/2204', 'display_name': 'Biomedical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11009', 'display_name': 'Catalysis for Biomass Conversion', 'score': 0.9998, 'subfield': {'id': 'https://openalex.org/subfields/2204', 'display_name': 'Biomedical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10192', 'display_name': 'Catalytic Processes in Materials Science', 'score': 0.9991, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11351', 'display_name': 'Catalysis and Hydrodesulfurization Studies', 'score': 0.9989, 'subfield': {'id': 'https://openalex.org/subfields/2210', 'display_name': 'Mechanical Engineering'}, 'field': {'id': 'https://openalex.org/fields/22', 'display_name': 'Engineering'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/glyceric-acid', 'display_name': 'Glyceric acid', 'score': 0.95996934}], 'concepts': [{'id': 'https://openalex.org/C2776655898', 'wikidata': 'https://www.wikidata.org/wiki/Q424906', 'display_name': 'Glyceric acid', 'level': 3, 'score': 0.95996934}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.84277827}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.7986709}, {'id': 'https://openalex.org/C118792377', 'wikidata': 'https://www.wikidata.org/wiki/Q108584245', 'display_name': 'Selectivity', 'level': 3, 'score': 0.79768026}, {'id': 'https://openalex.org/C2780881558', 'wikidata': 'https://www.wikidata.org/wiki/Q132501', 'display_name': 'Glycerol', 'level': 2, 'score': 0.77868056}, {'id': 'https://openalex.org/C32909587', 'wikidata': 'https://www.wikidata.org/wiki/Q11369', 'display_name': 'Molecule', 'level': 2, 'score': 0.5268121}, {'id': 'https://openalex.org/C155672457', 'wikidata': 'https://www.wikidata.org/wiki/Q61231', 'display_name': 'Nanoparticle', 'level': 2, 'score': 0.44059032}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.4285391}, {'id': 'https://openalex.org/C21951064', 'wikidata': 'https://www.wikidata.org/wiki/Q899212', 'display_name': 'Combinatorial chemistry', 'level': 1, 'score': 0.4083415}, {'id': 'https://openalex.org/C179104552', 'wikidata': 'https://www.wikidata.org/wiki/Q11165', 'display_name': 'Inorganic chemistry', 'level': 1, 'score': 0.33815846}, {'id': 'https://openalex.org/C42360764', 'wikidata': 'https://www.wikidata.org/wiki/Q83588', 'display_name': 'Chemical engineering', 'level': 1, 'score': 0.23257607}, {'id': 'https://openalex.org/C127413603', 'wikidata': 'https://www.wikidata.org/wiki/Q11023', 'display_name': 'Engineering', 'level': 0, 'score': 0.0}], 'mesh': [], 'locations_count': 2, 'locations': [{'is_oa': True, 'landing_page_url': 'https://doi.org/10.1002/anie.201000762', 'pdf_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201000762', 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/20461742', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': {'is_oa': True, 'landing_page_url': 'https://doi.org/10.1002/anie.201000762', 'pdf_url': 'https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201000762', 'source': {'id': 'https://openalex.org/S67393510', 'display_name': 'Angewandte Chemie International Edition', 'issn_l': '1433-7851', 'issn': ['1433-7851', '1521-3773'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320595', 'host_organization_name': 'Wiley', 'host_organization_lineage': ['https://openalex.org/P4310320595'], 'host_organization_lineage_names': ['Wiley'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': 'publishedVersion', 'is_accepted': True, 'is_published': True}, 'sustainable_development_goals': [{'id': 'https://metadata.un.org/sdg/6', 'score': 0.4, 'display_name': 'Clean water and sanitation'}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 28, 'referenced_works': ['https://openalex.org/W1975088029', 'https://openalex.org/W1975717961', 'https://openalex.org/W1977683397', 'https://openalex.org/W1977901738', 'https://openalex.org/W1985069924', 'https://openalex.org/W1985886708', 'https://openalex.org/W1988960968', 'https://openalex.org/W1995474291', 'https://openalex.org/W1998321859', 'https://openalex.org/W2012274225', 'https://openalex.org/W2016667724', 'https://openalex.org/W2018888765', 'https://openalex.org/W2019684550', 'https://openalex.org/W2024355474', 'https://openalex.org/W2029842534', 'https://openalex.org/W2030570477', 'https://openalex.org/W2034987712', 'https://openalex.org/W2045145310', 'https://openalex.org/W2054781839', 'https://openalex.org/W2058124745', 'https://openalex.org/W2074890984', 'https://openalex.org/W2078861604', 'https://openalex.org/W2081410167', 'https://openalex.org/W2104905103', 'https://openalex.org/W2134654245', 'https://openalex.org/W2144551564', 'https://openalex.org/W2943747291', 'https://openalex.org/W4236125934'], 'related_works': ['https://openalex.org/W4383226425', 'https://openalex.org/W3033182495', 'https://openalex.org/W2616359315', 'https://openalex.org/W2394315541', 'https://openalex.org/W2068116766', 'https://openalex.org/W2064162931', 'https://openalex.org/W2026226913', 'https://openalex.org/W1996423259', 'https://openalex.org/W1983542071', 'https://openalex.org/W136710584'], 'abstract_inverted_index': {'Skip': [0], 'the': [1, 12, 21, 37, 57, 69, 80, 102, 130, 151, 201, 208, 245, 252, 274, 279, 296, 300, 331, 345, 361, 369, 404, 420, 424, 433, 444, 454, 493, 515, 536, 539, 567, 617, 636, 661, 673, 711, 726, 735, 743, 759, 855, 863, 867, 872, 878, 888, 916, 922, 925, 946, 973, 979, 983, 990, 1045, 1060, 1085, 1096, 1114, 1125, 1132, 1135, 1141, 1169, 1182, 1203, 1211, 1220, 1235, 1238, 1264, 1290, 1302, 1310, 1321, 1360, 1390, 1394, 1407, 1463, 1468, 1478, 1488, 1525, 1530, 1535, 1553, 1569, 1579, 1589, 1594, 1598, 1602, 1609, 1612, 1642, 1656, 1671, 1681, 1687, 1700, 1703, 1706, 1712, 1718, 1739, 1753, 1766, 1773, 1777, 1782, 1807, 1814, 1822, 1830, 1857, 1880, 1885, 1923, 1933, 1943, 1955, 1959], 'bases!': [2], 'H-mordenite-supported': [3, 727], 'PtAu': [4, 45], 'nanoparticles': [5, 46, 289, 1199, 1255, 1386, 1453, 1503, 1736], 'are': [6, 88, 140, 273, 385, 1020, 1550, 1742, 1902, 1909, 1917], 'highly': [7, 99, 191, 311], 'active': [8, 93, 312, 1056, 1834], 'and': [9, 66, 84, 94, 122, 142, 155, 236, 241, 256, 270, 287, 313, 328, 372, 450, 474, 482, 503, 620, 654, 668, 763, 1049, 1077, 1137, 1146, 1247, 1282, 1376, 1457, 1507, 1576, 1597, 1684, 1813, 1839, 1852, 1877], 'selective': [10, 100, 218, 315], 'in': [11, 42, 316, 322, 349, 681, 710, 742, 753, 945, 972, 978, 1043, 1066, 1113, 1164, 1234, 1270, 1301, 1320, 1372, 1382, 1445, 1487, 1524, 1552, 1591, 1632, 1686, 1714, 1776], 'oxidation': [13, 71, 219, 247, 280, 301, 340, 351, 370, 455, 516, 785, 894, 1115, 1838], 'of': [14, 24, 40, 72, 104, 120, 153, 200, 210, 220, 248, 281, 302, 334, 360, 364, 378, 383, 388, 396, 407, 423, 429, 436, 447, 456, 465, 517, 530, 571, 580, 638, 647, 664, 745, 750, 779, 857, 866, 887, 891, 903, 918, 948, 975, 981, 999, 1063, 1087, 1116, 1124, 1134, 1144, 1184, 1193, 1206, 1237, 1243, 1304, 1312, 1416, 1428, 1467, 1490, 1501, 1512, 1532, 1560, 1568, 1574, 1604, 1611, 1618, 1625, 1641, 1647, 1651, 1658, 1673, 1689, 1694, 1705, 1722, 1755, 1769, 1784, 1790, 1809, 1860, 1887, 1897, 1937], 'glycerol': [15, 109, 221, 249, 457, 594, 639, 784, 1305, 1674, 1747, 1893], 'under': [16, 110, 137, 267, 338, 399, 438, 484, 961, 1119], 'acidic': [17, 111, 138, 401, 439, 475, 674, 962, 1046, 1064], 'conditions,': [18, 255, 381, 440], 'which': [19, 1044], 'allows': [20, 403, 1781], 'direct': [22, 405], 'preparation': [23], 'free': [25, 389], 'acids': [26, 384], '(see': [27, 1680, 1879], 'picture).': [28], 'The': [29, 217, 239, 748, 777, 884, 901, 1122, 1197, 1241, 1927], 'high': [30, 64, 170, 1719], 'selectivity': [31, 67, 171, 181, 422, 713, 744, 1308, 1429, 1779, 1789, 1851], 'for': [32, 59, 68, 207, 244, 278, 299, 514, 635, 656, 725, 770, 783, 877, 933, 1252, 1275, 1293, 1400, 1932, 1958], 'C3': [33, 106, 715, 1431], 'compounds': [34], 'results': [35, 731, 1362, 1716], 'from': [36, 108, 134, 146, 213, 994, 1035, 1436, 1584, 1675, 1717], 'negligible': [38], 'formation': [39, 103, 406, 646, 684, 1183, 1311, 1375, 1842], 'H2O2,': [41], 'contrast': [43], 'to': [44, 90, 166, 172, 225, 309, 326, 336, 367, 606, 631, 686, 691, 714, 718, 914, 1012, 1092, 1263, 1406, 1421, 1430, 1433, 1477, 1534, 1540, 1586, 1638, 1677, 1744, 1749, 1805, 1824, 1845, 1867, 1892, 1899, 1954], 'supported': [47, 290, 1410, 1454, 1504, 1737], 'on': [48, 251, 291, 453, 470, 522, 542, 574, 582, 672, 689, 758, 786, 1131, 1157, 1219, 1288, 1359, 1366, 1389, 1411, 1455, 1458, 1492, 1505, 1514, 1620, 1738, 1759, 1819], 'activated': [49, 292], 'carbon.': [50], 'Herein,': [51], 'we': [52, 87, 441, 911, 1019, 1189, 1460, 1665, 1865], 'report': [53], 'progress': [54], 'towards': [55, 101, 1309], 'eliminating': [56], 'need': [58], 'a': [60, 169, 190, 355, 365, 376, 427, 463, 478, 624, 678, 739, 860, 930, 995, 1013, 1031, 1040, 1088, 1093, 1107, 1173, 1191, 1248, 1267, 1317, 1369, 1413, 1441, 1521, 1572, 1639, 1691, 1788, 1825, 1863], 'base': [61, 366], 'while': [62], 'maintaining': [63], 'activity': [65, 240, 627, 754, 766, 1272, 1417, 1466, 1599, 1695, 1715], 'aqueous-phase': [70], 'glycerol.': [73, 665, 868], 'We': [74], 'have': [75], 'discovered': [76], 'that': [77, 97, 129, 158, 180, 195, 415, 734, 1008, 1028, 1084, 1154, 1180, 1398, 1462, 1566, 1607, 1780, 1801, 1843, 1884], 'by': [78, 159, 477, 510, 551, 906, 989, 1100, 1167, 1177, 1202, 1210, 1232, 1392, 1425, 1669, 1802, 1922, 1942], 'using': [79, 160, 323, 379, 519, 1244, 1770, 1874], 'right': [81], 'alloy': [82, 1195, 1276], 'nanoparticle': [83, 451, 1094], 'support': [85, 448, 496, 736, 761, 861, 931, 1221, 1292, 1774, 1831], 'material,': [86], 'able': [89, 1743], 'prepare': [91], 'an': [92, 393, 400, 498, 708, 1055, 1160, 1426, 1648, 1833], 'durable': [95], 'catalyst': [96, 425, 1042, 1156, 1409, 1815, 1828, 1864], 'is': [98, 115, 164, 189, 196, 330, 492, 559, 1026, 1081, 1273, 1889, 1929], 'oxidized': [105], 'molecules': [107, 144], 'conditions.': [112, 486, 1757], 'This': [113, 557], 'discovery': [114], 'significant': [116, 645, 679, 1268, 1299, 1370, 1380], 'because': [117, 359, 490, 1646], 'previous': [118, 1151], 'investigations': [119], 'Pd': [121, 286, 1104], 'Pt': [123, 161, 288, 327, 1106, 1227, 1405, 1533, 1575, 1626], 'catalysts': [124, 136, 162, 263, 277, 605, 622, 659, 670, 687, 1287, 1365, 1378, 1470], 'at': [125, 524, 588, 609, 966, 1074, 1793], 'pH': [126, 1075, 1704], '2–4': [127], 'reported': [128, 509, 1112], 'main': [131], 'products': [132, 1323, 1723], 'derived': [133], 'these': [135, 604, 1294], 'conditions': [139, 269, 341, 417, 963], 'C1': [141, 648, 682, 698, 803, 1322, 1335, 1373, 1446], 'C2': [143], 'produced': [145, 1010], 'C\uf8ffC': [147, 879, 1846], 'bond': [148, 880, 1847], 'scission.1–3': [149], 'Furthermore,': [150, 704, 1449], 'groups': [152], 'Claus': [154], 'Hutchings': [156], 'showed': [157, 602, 1296, 1368, 1379, 1761, 1883], 'it': [163, 491, 1004, 1025, 1797], 'possible': [165], 'obtain': [167], 'quite': [168], 'hydroxyacetone': [173], '(C3': [174], 'molecule)': [175], 'or': [176, 1105, 1128, 1162, 1627, 1914, 1935], 'hydroxypyruvic': [177], 'acid,': [178, 232, 235], 'but': [179, 304, 562, 1306, 1765, 1911], 'rapidly': [182, 970], 'declines': [183], 'with': [184, 265, 342, 352, 497, 898, 1103, 1140, 1316, 1440, 1482, 1529, 1787], 'increasing': [185, 1670, 1699, 1726], 'conversion.1,': [186], '4–6': [187], 'Glycerol': [188], 'functionalized': [192], 'bioderived': [193], 'molecule': [194, 1170], 'recognized': [197], 'as': [198, 230, 344, 426, 549, 651, 859, 929, 987, 1039, 1222, 1397, 1772, 1862, 1904, 1920], 'one': [199], 'most': [202, 275], 'promising': [203], 'chemical': [204], 'building': [205], 'blocks': [206], 'synthesis': [209], 'fine': [211], 'chemicals': [212], 'renewable': [214], 'sources.7,': [215], '9': [216, 845], 'has': [222, 755, 790, 1068, 1256, 1798], 'been': [223, 756, 793, 1069, 1257, 1799], 'shown': [224, 308, 1800], 'produce': [226], 'valuable': [227], 'products,': [228, 649, 716], 'such': [229, 650], 'glyceric': [231, 1313, 1750, 1785], 'hydroxyacetone,': [233], 'tartronic': [234, 723], 'ketomalonic': [237], 'acid.': [238], 'product': [242, 683, 699, 1374, 1447], 'distribution': [243], 'catalytic': [246, 585, 1271, 1383, 1633], 'depend': [250], 'catalyst,': [253, 1644], 'reaction': [254, 873, 889, 1033, 1480, 1708], 'oxidant': [257], 'source.7–9': [258], 'In': [259, 943, 1058, 1098, 1261, 1653, 1733], 'general,': [260], 'carbon-supported': [261], 'metal': [262, 1090, 1213], 'combined': [264], 'dioxygen': [266], 'basic': [268, 380, 416, 504, 692, 1756], 'moderate': [271], 'temperature': [272], 'investigated': [276, 298, 489], 'glycerol.1,': [282], '4–6,': [283], '10,': [284], '11': [285], 'carbon': [293], '(AC)': [294], 'were': [295, 468, 1200, 1387], 'first': [297, 885, 1217], 'glycerol,': [303], 'gold': [305, 353, 495, 537, 619, 667, 1207, 1364, 1536, 1827], 'was': [306, 488, 507, 544, 644, 706, 927, 938, 955, 1111, 1216, 1228, 1418, 1516, 1582, 1629, 1710, 1811], 'recently': [307, 508, 1175, 1258], 'be': [310, 413, 607, 875, 1006, 1497, 1636, 1662, 1730, 1952], 'very': [314, 625, 935], 'this': [317, 610, 746, 904, 1654], 'reaction.1–10': [318], 'A': [319, 1509, 1871], 'key': [320, 740], 'advantage': [321], 'gold,': [324], 'compared': [325, 630, 685], 'Pd,': [329], 'improved': [332], 'resistance': [333], 'Au': [335, 521, 572, 581, 1102, 1408, 1628, 1804], 'overoxidation': [337], 'liquid-phase': [339], 'O2': [343, 907], 'oxidant.1,': [346], '10–13': [347], 'However,': [348, 642, 1578], 'alcohol': [350, 893, 1837], 'catalysts,': [354], 'severe': [356], 'limitation': [357], 'arises': [358], 'required': [362], 'addition': [363, 529, 1531], 'improve': [368], 'kinetics': [371], 'reduce': [373], 'deactivation.': [374], 'As': [375, 1622, 1702], 'consequence': [377], 'salts': [382], 'obtained': [386], 'instead': [387], 'carboxylic': [390], 'acids.': [391], 'From': [392], 'industrial': [394, 434], 'point': [395, 501], 'view,': [397], 'working': [398], 'regime': [402], 'acid': [408, 653, 800, 802, 1314, 1332, 1334, 1751, 1786], 'products.': [409], 'It': [410, 1080], 'should': [411, 1951], 'also': [412, 707, 1307], 'noted': [414], 'could': [418, 1005, 1661, 1729], 'modify': [419, 1608], 'intrinsic': [421], 'result': [428], 'base-catalyzed': [430], 'interconversions.': [431], 'Given': [432], 'importance': [435, 1242, 1898], 'operating': [437], 'began': [442], 'investigating': [443], 'synergistic': [445, 1109], 'effect': [446, 1110, 1126, 1657, 1768], 'material': [449, 737, 932], 'composition': [452], 'without': [458, 527, 1752], 'base.': [459], 'For': [460, 1149], 'comparison': [461, 1262], 'purposes,': [462], 'series': [464, 1192], 'monometallic': [466, 520, 618, 658, 728, 1265], 'clusters': [467, 1208, 1537, 1564, 1570], 'deposited': [469, 671, 688, 1218], 'AC,': [471, 1289], 'TiO2,': [472], 'MgAl2O4,': [473], 'H-mordenite': [476, 543, 676, 858, 926, 1067, 1391, 1459, 1493, 1515, 1741, 1820], 'sol': [479], 'immobilization': [480], 'technique': [481], 'tested': [483], 'similar': [485, 1022, 1762], 'TiO2': [487], 'prototypical': [494], 'intermediate': [499], 'isoelectric': [500], '(IEP),': [502], 'MgAl2O4': [505, 523], '(IEP=11.8)': [506], 'Christensen': [511], 'et': [512], 'al.': [513], 'ethanol': [518], '100': [525, 967, 1078], '°C': [526, 590], 'any': [528, 1938], 'base.14,': [531], '15': [532], 'Upon': [533], 'comparing': [534, 1021, 1451], 'just': [535], 'clusters,': [538, 1266], 'average': [540, 1526], 'diameter': [541, 570], '(3.76±1.90)': [545, 1539], 'nm': [546], '(Figure': [547, 1001, 1484], '1),': [548], 'determined': [550], 'scanning': [552], 'transmission': [553], 'electron': [554], 'microscopy': [555], '(STEM).': [556], 'value': [558], 'slightly': [560], 'larger,': [561], 'within': [563], 'experimental': [564], 'error,': [565], 'than': [566, 1016, 1948], 'corresponding': [568, 1956], 'mean': [569], 'particles': [573, 782], 'AC': [575, 1158, 1456, 1506, 1760], '[(2.98±1.31)': [576], 'nm].': [577], 'STEM': [578, 1518, 1616], 'image': [579, 1617], 'H-mordenite.': [583, 1508, 1621], 'Initial': [584], 'testing': [586], 'performed': [587, 912], '50': [589], '(0.3': [591], 'M': [592, 1679], 'aqueous': [593], 'solution,': [595], 'glycerol/metal': [596], 'ratio': [597, 1581], '500': [598], '(mol/mol),': [599], 'pO2=3': [600], 'atm)': [601], 'all': [603, 657, 1567], 'inactive': [608], 'temperature.': [611], 'At': [612], 'elevated': [613], 'temperatures': [614], '(100': [615], '°C)': [616], 'palladium': [621], 'exhibited': [623, 677], 'low': [626], '(<8': [628], '%),': [629, 634], 'platinum': [632, 669], '(78': [633], 'conversion': [637, 1023, 1303, 1496], '(Table': [640, 1325], '1).': [641, 703], 'there': [643, 705], 'formic': [652], 'CO2,': [655], 'through': [660], 'oxidative': [662, 864], 'degradation': [663, 865, 984], 'Surprisingly,': [666], 'oxide': [675], 'reduction': [680, 902, 1250], 'neutral': [690], 'supports': [693, 789], '(5–10': [694], 'versus': [695], '41–51': [696], '%': [697, 720, 806, 813, 820, 827, 834, 841, 848, 1280, 1285, 1338, 1345, 1352, 1435, 1438, 1443, 1792], 'formation,': [700], 'respectively;': [701], 'Table': [702], 'enhancement': [709, 1269, 1415, 1427], 'overall': [712], 'up': [717, 1432], '79–81': [719], '(glyceric': [721], '+': [722], 'acids)': [724], 'catalysts.': [729], 'These': [730], 'further': [732], 'confirm': [733, 1601], 'plays': [738, 1832], 'role': [741, 749, 1835], 'reaction.10': [747], 'particle': [751, 1527, 1592], 'size': [752, 1528], 'studied': [757], 'same': [760, 1395, 1464, 1479], '(AC),': [762], 'revealed': [764], 'higher': [765], '(and': [767, 1696], 'less': [768], 'selectivity)': [769, 1697], 'smaller': [771], 'particles.10,': [772], '11,': [773], '13,': [774], '16,': [775], '17': [776], 'behavior': [778, 1634], 'similarly': [780], 'sized': [781], 'substantially': [787], 'different': [788, 1032], 'not': [791, 1297, 1475, 1890, 1912, 1930], 'yet': [792], 'reported.': [794], 'Catalyst': [795, 1327], 'Conv.[b]': [796, 1328], 'Selectivity': [797, 1329], '[%]': [798, 1330], 'Glyceric': [799, 1331], 'Tartronic': [801, 1333], 'products[c]': [804, 1336], '1': [805, 812, 819, 826, 833, 840, 847, 996, 1337, 1344, 1349, 1351, 1678], 'Au/AC': [807, 949], '3': [808], '39': [809], '–': [810, 1342], '51': [811], 'Pd/AC': [814], '5': [815, 817, 843, 846], '43': [816], '47': [818], 'Pt/AC': [821], '78': [822], '45': [823], '7': [824, 838], '46': [825], 'Au/MgAl2O4': [828], '6': [829, 831], '35': [830], '41': [832], 'Au/TiO2': [835], '8': [836], '38': [837], '32': [839], 'Au/H-mordenite': [842, 982, 1009, 1029], '70': [844, 1354, 1422], 'Pt/H-mordenite': [849], '20': [850, 1561], '79': [851, 1348], '2': [852, 1076, 1356, 1442, 1472], '10': [853, 1357], 'Clearly': [854], 'use': [856, 1754, 1859, 1886], 'reduces': [862], 'H2O2': [869, 919, 937, 954, 969, 1000, 1011, 1072, 1841], 'formed': [870, 1324], 'during': [871, 921, 1836], 'can': [874, 1052, 1494, 1635], 'responsible': [876, 1931], 'scission.11,': [881], '18,': [882], '19': [883], 'step': [886], 'mechanism': [890, 1034], 'Au-catalyzed': [892], 'involves': [895], 'hydride': [896], 'abstraction': [897], 'AuH': [899], 'formation.20': [900], 'species': [905], 'forms': [908], 'H2O2.': [909], 'Therefore,': [910], 'experiments': [913], 'determine': [915], 'amount': [917], 'present': [920], 'reactions.': [923], 'When': [924], 'employed': [928], 'Au,': [934], 'little': [936], 'detected': [939, 956], '(0.025': [940], 'mmol': [941, 958], 'L−1).': [942, 959], 'contrast,': [944], 'case': [947, 1489, 1655, 1688], 'almost': [950], '30': [951], 'times': [952], 'more': [953], '(0.70': [957], 'Moreover,': [960, 1796], '(pH': [964], '2)': [965], '°C,': [968], 'degrades': [971], 'presence': [974, 980, 1236, 1603], 'Au/AC,': [976, 1036], 'whereas': [977], 'proceeds': [985], 'slower,': [986], 'evidenced': [988], 'blank': [991], 'experiment': [992], 'starting': [993], 'mM': [997], 'solution': [998], '2).': [1002, 1326], 'Thus,': [1003, 1664], 'concluded': [1007], 'lesser': [1014], 'extent': [1015], 'Au/AC.': [1017], 'Since': [1018], 'rates,': [1024], 'likely': [1027], 'follows': [1030], 'possibly': [1037, 1053, 1645], 'acting': [1038], 'bifunctional': [1041], 'sites': [1047, 1065], '(Broensted': [1048], 'Lewis': [1050], 'type)': [1051], 'play': [1054], 'role.': [1057], 'fact': [1059], 'peculiar': [1061], 'nature': [1062, 1133], 'reported.21,': [1070], '22': [1071], 'decomposition': [1073], '°C.': [1079], 'well': [1082], 'known': [1083], 'introduction': [1086], 'second': [1089, 1212], 'component': [1091], 'changes': [1095], 'activity.': [1097], 'fact,': [1099], 'alloying': [1101, 1803], 'strong': [1108, 1414], 'alcohol,': [1117], 'even': [1118], 'neutral/acidic': [1120], 'conditions.23–25': [1121], 'magnitude': [1123], '(positive': [1127], 'negative)': [1129], 'depends': [1130], 'reactant': [1136, 1659], 'its': [1138], 'match': [1139], 'geometrical/electronic': [1142], 'requisites': [1143], 'AuPd': [1145, 1187, 1283], 'AuPt': [1147, 1155, 1278, 1377, 1385, 1452, 1491, 1502, 1513, 1605, 1619, 1735, 1758, 1818], 'catalysts.26': [1148], 'example,': [1150], 'reports': [1152], 'show': [1153], 'exhibits': [1159], 'increase': [1161, 1523, 1590], 'decrease': [1163, 1319, 1371, 1444, 1693, 1713], 'reactivity': [1165], 'simply': [1166], 'changing': [1168], 'reacted.26': [1171], 'Following': [1172], 'procedure': [1174, 1396], 'developed': [1176], 'our': [1178], 'group': [1179], 'ensures': [1181], 'homogeneously': [1185], 'alloyed': [1186, 1254], 'nanoparticles,': [1188], 'prepared': [1190, 1201, 1388], 'Au-based': [1194], 'catalysts.27': [1196], 'bimetallic': [1198], 'sequential': [1204], 'deposition': [1205], 'followed': [1209], 'component.': [1214], 'Gold': [1215], 'poly(vinyl': [1223], 'alcohol)': [1224], '(PVA)-protected': [1225], 'nanoclusters.': [1226], 'then': [1229], 'slowly': [1230], 'reduced': [1231], 'H2': [1233], 'Au/support': [1239], 'material.': [1240], 'PVA-protected': [1245], 'nanoclusters': [1246], 'slow': [1249], 'process': [1251], 'obtaining': [1253], 'reported.28,': [1259], '29': [1260], 'observed': [1274, 1419, 1461, 1685], 'nanoparticles.': [1277, 1402], '(58': [1279, 1420], 'conversion)': [1281, 1286], '(12': [1284], 'typical': [1291], 'reactions,': [1295], 'only': [1298], 'increases': [1300, 1381], 'along': [1315, 1439], 'concomitant': [1318], 'AuPd(6:4)/AC': [1339], '12': [1340, 1350], '65': [1341], '24': [1343], 'AuPt(6:4)/AC': [1346], '58': [1347], 'AuPt(6:4)/H-mordenite': [1353], '83': [1355], 'Based': [1358], 'above': [1361], 'where': [1363, 1829], 'mordenite': [1367, 1771], 'activity,': [1384, 1764], 'following': [1393], 'used': [1399], 'AC-supported': [1401], 'By': [1403], 'adding': [1404], 'H-mordenite,': [1412], '%)': [1423], 'accompanied': [1424], '85': [1434], '80': [1437], 'formation.': [1448], 'upon': [1450, 1698], 'initial': [1465, 1763], 'two': [1469], '(after': [1471], 'h)': [1473], 'did': [1474], 'correspond': [1476], 'profile': [1481, 1500], 'time': [1483], '3).': [1485], 'Only': [1486], 'full': [1495, 1510, 1794], 'achieved.': [1498], 'Reaction': [1499], 'characterization': [1511], 'performed.': [1517], 'data': [1519, 1549, 1600], 'indicated': [1520, 1565], 'slight': [1522, 1692], '(from': [1538], '(4.0±1.80)': [1541], 'nm;': [1542], 'Figure': [1543], '4).': [1544], 'X-ray': [1545], 'photoelectron': [1546], 'spectroscopy': [1547, 1557], '(XPS)': [1548], 'presented': [1551], 'Supporting': [1554, 1682, 1881], 'Information.': [1555], 'Energy-dispersive': [1556], '(EDS)': [1558], 'analysis': [1559], 'randomly': [1562], 'selected': [1563], 'contained': [1571], 'mixture': [1573], 'Au.': [1577], 'Au/Pt': [1580], 'inhomogeneous': [1583], 'cluster': [1585], 'cluster.': [1587], 'Regardless,': [1588], 'size,': [1593], 'EDS': [1595], 'data,': [1596], 'alloys': [1606], 'properties': [1610, 1721], 'resulting': [1613], 'catalyst.': [1614], 'Representative': [1615], 'no': [1623], 'leaching': [1624, 1808], 'observed,': [1630], 'differences': [1631], 'ascribed': [1637], 'deactivation': [1640], '“on-carbon”': [1643], 'irreversible': [1649], 'adsorption': [1650], 'by-products.': [1652], 'concentration': [1660, 1672], 'important.': [1663], 'carried': [1666], 'out': [1667], 'tests': [1668], '0.3': [1676], 'Information)': [1683, 1882], 'AuPt/H-mordenite': [1690, 1861, 1888], 'concentration.': [1701], 'final': [1707], 'mixtures': [1709], 'similar,': [1711], 'chelating': [1720], 'that,': [1724], 'when': [1725], 'their': [1727], 'concentration,': [1728], 'irreversibly': [1731], 'adsorbed.': [1732], 'summary,': [1734], 'zeolite': [1740], 'selectively': [1745], 'oxidize': [1746], 'directly': [1748], 'major': [1767], 'lies': [1775], 'enhanced': [1778], 'production': [1783], '81': [1791], 'conversion.': [1795], 'Pt,': [1806], 'metals': [1810], 'avoided': [1812], 'life': [1816], 'improved.': [1817], 'opens': [1821], 'way': [1823], 'new-generation': [1826], 'prevents': [1840], 'leads': [1844], 'scission,': [1848], 'thus': [1849], 'improving': [1850], 'materials': [1853], 'utilization.': [1854], 'To': [1855], 'assess': [1856], 'general': [1858], 'plan': [1866], 'test': [1868], 'other': [1869], 'substrates.': [1870], 'preliminary': [1872], 'study': [1873], 'ethylene': [1875], 'glycol': [1876], '1,3-propanediol': [1878], 'limited': [1891], 'oxidation.': [1894], 'Detailed': [1895], 'facts': [1896], 'specialist': [1900], 'readers': [1901], 'published': [1903], '”Supporting': [1905], 'Information”.': [1906], 'Such': [1907], 'documents': [1908], 'peer-reviewed,': [1910], 'copy-edited': [1913], 'typeset.': [1915], 'They': [1916], 'made': [1918], 'available': [1919], 'submitted': [1921], 'authors.': [1924, 1944], 'Please': [1925], 'note:': [1926], 'publisher': [1928], 'content': [1934], 'functionality': [1936], 'supporting': [1939], 'information': [1940], 'supplied': [1941], 'Any': [1945], 'queries': [1946], '(other': [1947], 'missing': [1949], 'content)': [1950], 'directed': [1953], 'author': [1957], 'article.': [1960]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2095699355', 'counts_by_year': [{'year': 2024, 'cited_by_count': 5}, {'year': 2023, 'cited_by_count': 14}, {'year': 2022, 'cited_by_count': 5}, {'year': 2021, 'cited_by_count': 8}, {'year': 2020, 'cited_by_count': 13}, {'year': 2019, 'cited_by_count': 15}, {'year': 2018, 'cited_by_count': 11}, {'year': 2017, 'cited_by_count': 17}, {'year': 2016, 'cited_by_count': 9}, {'year': 2015, 'cited_by_count': 20}, {'year': 2014, 'cited_by_count': 28}, {'year': 2013, 'cited_by_count': 26}, {'year': 2012, 'cited_by_count': 31}], 'updated_date': '2024-12-10T08:22:27.830385', 'created_date': '2016-06-24'}