Title: The enthalpies of formation of FeWO4, MnWO4, and their solid solutions
Abstract: The enthalpy of mixing to form the {(1 − x)FeWO4 + xMnWO4} solid solution has been determined by high-temperature solution calorimetry, by way of an especially designed (0.5LiBO2 + 0.5NaBO2) molten bath. Our ΔH value for FeWO4 is in good agreement with literature values obtained by the same method, but differs from values deduced from measurements of the standard Gibbs free energy of formation. A negative enthalpy of mixing is reported.
Publication Year: 1980
Publication Date: 1980-07-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 6
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