Title: Allylruthenium(<scp>IV</scp>) Complexes as Highly Efficient ROMP Catalysts
Abstract:First activate, then polymerize. This is the way that ruthenium complexes such as 1 can be used to catalyze the ring-opening metathesis polymerization efficiently. Diazoalkanes serve as activating age...First activate, then polymerize. This is the way that ruthenium complexes such as 1 can be used to catalyze the ring-opening metathesis polymerization efficiently. Diazoalkanes serve as activating agents and depending on their substitution pattern subequivalent or excess amounts are required. When ethyl diazoacetate is used, turnover frequency values above 105 h−1 have been achieved in the ring-opening metathesis polymerization of norbornene.Read More
Publication Year: 1996
Publication Date: 1996-06-03
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 42
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