Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W2092710284', 'doi': 'https://doi.org/10.1021/ja308700t', 'title': 'Role of Proton-Coupled Electron Transfer in the Redox Interconversion between Benzoquinone and Hydroquinone', 'display_name': 'Role of Proton-Coupled Electron Transfer in the Redox Interconversion between Benzoquinone and Hydroquinone', 'publication_year': 2012, 'publication_date': '2012-11-01', 'ids': {'openalex': 'https://openalex.org/W2092710284', 'doi': 'https://doi.org/10.1021/ja308700t', 'mag': '2092710284', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/23113818'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/ja308700t', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S111155417', 'display_name': 'Journal of the American Chemical Society', 'issn_l': '0002-7863', 'issn': ['0002-7863', '1520-5126', '1943-2984'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5052639398', 'display_name': 'Na Song', 'orcid': 'https://orcid.org/0000-0002-2609-4653'}, 'institutions': [{'id': 'https://openalex.org/I114027177', 'display_name': 'University of North Carolina at Chapel Hill', 'ror': 'https://ror.org/0130frc33', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I114027177']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Na Song', 'raw_affiliation_strings': ['Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States', 'institution_ids': ['https://openalex.org/I114027177']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5058408056', 'display_name': 'Christopher J. Gagliardi', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I114027177', 'display_name': 'University of North Carolina at Chapel Hill', 'ror': 'https://ror.org/0130frc33', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I114027177']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Christopher J. Gagliardi', 'raw_affiliation_strings': ['Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States', 'institution_ids': ['https://openalex.org/I114027177']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5022584839', 'display_name': 'Robert A. Binstead', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I114027177', 'display_name': 'University of North Carolina at Chapel Hill', 'ror': 'https://ror.org/0130frc33', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I114027177']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Robert A. Binstead', 'raw_affiliation_strings': ['Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States', 'institution_ids': ['https://openalex.org/I114027177']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5020808232', 'display_name': 'Ming‐Tian Zhang', 'orcid': 'https://orcid.org/0000-0001-8808-9641'}, 'institutions': [{'id': 'https://openalex.org/I114027177', 'display_name': 'University of North Carolina at Chapel Hill', 'ror': 'https://ror.org/0130frc33', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I114027177']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Ming-Tian Zhang', 'raw_affiliation_strings': ['Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States', 'institution_ids': ['https://openalex.org/I114027177']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5024622895', 'display_name': 'H. Holden Thorp', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I114027177', 'display_name': 'University of North Carolina at Chapel Hill', 'ror': 'https://ror.org/0130frc33', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I114027177']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Holden Thorp', 'raw_affiliation_strings': ['Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States', 'institution_ids': ['https://openalex.org/I114027177']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5089516413', 'display_name': 'Thomas J. Meyer', 'orcid': 'https://orcid.org/0000-0002-7006-2608'}, 'institutions': [{'id': 'https://openalex.org/I114027177', 'display_name': 'University of North Carolina at Chapel Hill', 'ror': 'https://ror.org/0130frc33', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I114027177']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'Thomas J. Meyer', 'raw_affiliation_strings': ['Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina#R#27599-3290, United States', 'institution_ids': ['https://openalex.org/I114027177']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 1, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 1.671, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 53, 'citation_normalized_percentile': {'value': 0.862907, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 95, 'max': 96}, 'biblio': {'volume': '134', 'issue': '45', 'first_page': '18538', 'last_page': '18541'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11747', 'display_name': 'Dioxygen Activation at Metalloenzyme Active Sites', 'score': 0.9998, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11747', 'display_name': 'Dioxygen Activation at Metalloenzyme Active Sites', 'score': 0.9998, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10303', 'display_name': 'Molecular Mechanisms of Photosynthesis and Photoprotection', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/1312', 'display_name': 'Molecular Biology'}, 'field': {'id': 'https://openalex.org/fields/13', 'display_name': 'Biochemistry, Genetics and Molecular Biology'}, 'domain': {'id': 'https://openalex.org/domains/1', 'display_name': 'Life Sciences'}}, {'id': 'https://openalex.org/T10903', 'display_name': 'Role of Porphyrins and Phthalocyanines in Materials Chemistry', 'score': 0.9994, 'subfield': {'id': 'https://openalex.org/subfields/2505', 'display_name': 'Materials Chemistry'}, 'field': {'id': 'https://openalex.org/fields/25', 'display_name': 'Materials Science'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/hydroquinone', 'display_name': 'Hydroquinone', 'score': 0.95756245}, {'id': 'https://openalex.org/keywords/benzoquinone', 'display_name': 'Benzoquinone', 'score': 0.8108928}, {'id': 'https://openalex.org/keywords/electron-acceptor', 'display_name': 'Electron acceptor', 'score': 0.61895365}, {'id': 'https://openalex.org/keywords/proton-coupled-electron-transfer', 'display_name': 'Proton-Coupled Electron Transfer', 'score': 0.587729}, {'id': 'https://openalex.org/keywords/1,4-benzoquinone', 'display_name': '1,4-Benzoquinone', 'score': 0.5814695}, {'id': 'https://openalex.org/keywords/phosphoric-acid', 'display_name': 'Phosphoric acid', 'score': 0.56267995}, {'id': 'https://openalex.org/keywords/electron-donor', 'display_name': 'Electron donor', 'score': 0.4856871}, {'id': 'https://openalex.org/keywords/chloranilic-acid', 'display_name': 'Chloranilic acid', 'score': 0.45248774}], 'concepts': [{'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.9705946}, {'id': 'https://openalex.org/C2777550763', 'wikidata': 'https://www.wikidata.org/wiki/Q419164', 'display_name': 'Hydroquinone', 'level': 2, 'score': 0.95756245}, {'id': 'https://openalex.org/C55904794', 'wikidata': 'https://www.wikidata.org/wiki/Q82682', 'display_name': 'Redox', 'level': 2, 'score': 0.86150944}, {'id': 'https://openalex.org/C2779686393', 'wikidata': 'https://www.wikidata.org/wiki/Q509361', 'display_name': 'Benzoquinone', 'level': 2, 'score': 0.8108928}, {'id': 'https://openalex.org/C54516573', 'wikidata': 'https://www.wikidata.org/wiki/Q2294', 'display_name': 'Proton', 'level': 2, 'score': 0.6812784}, {'id': 'https://openalex.org/C110010208', 'wikidata': 'https://www.wikidata.org/wiki/Q7252048', 'display_name': 'Proton-coupled electron transfer', 'level': 3, 'score': 0.6799643}, {'id': 'https://openalex.org/C123669783', 'wikidata': 'https://www.wikidata.org/wiki/Q902898', 'display_name': 'Electron transfer', 'level': 2, 'score': 0.6658272}, {'id': 'https://openalex.org/C2900893', 'wikidata': 'https://www.wikidata.org/wiki/Q1231592', 'display_name': 'Electron acceptor', 'level': 2, 'score': 0.61895365}, {'id': 'https://openalex.org/C75473681', 'wikidata': 'https://www.wikidata.org/wiki/Q188651', 'display_name': 'Photochemistry', 'level': 1, 'score': 0.5817586}, {'id': 'https://openalex.org/C2776297863', 'wikidata': 'https://www.wikidata.org/wiki/Q402719', 'display_name': '1,4-Benzoquinone', 'level': 3, 'score': 0.5814695}, {'id': 'https://openalex.org/C2776622989', 'wikidata': 'https://www.wikidata.org/wiki/Q184782', 'display_name': 'Phosphoric acid', 'level': 2, 'score': 0.56267995}, {'id': 'https://openalex.org/C2778148179', 'wikidata': 'https://www.wikidata.org/wiki/Q911571', 'display_name': 'Electron donor', 'level': 3, 'score': 0.4856871}, {'id': 'https://openalex.org/C2778603181', 'wikidata': 'https://www.wikidata.org/wiki/Q3277941', 'display_name': 'Chloranilic acid', 'level': 2, 'score': 0.45248774}, {'id': 'https://openalex.org/C2780643102', 'wikidata': 'https://www.wikidata.org/wiki/Q412382', 'display_name': 'Quinone', 'level': 2, 'score': 0.44884288}, {'id': 'https://openalex.org/C179104552', 'wikidata': 'https://www.wikidata.org/wiki/Q11165', 'display_name': 'Inorganic chemistry', 'level': 1, 'score': 0.29272246}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.20274335}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.18104789}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.13506001}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C62520636', 'wikidata': 'https://www.wikidata.org/wiki/Q944', 'display_name': 'Quantum mechanics', 'level': 1, 'score': 0.0}], 'mesh': [{'descriptor_ui': 'D016227', 'descriptor_name': 'Benzoquinones', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': True}, {'descriptor_ui': 'D006873', 'descriptor_name': 'Hydroquinones', 'qualifier_ui': 'Q000737', 'qualifier_name': 'chemistry', 'is_major_topic': True}, {'descriptor_ui': 'D011522', 'descriptor_name': 'Protons', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': True}, {'descriptor_ui': 'D016227', 'descriptor_name': 'Benzoquinones', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D004579', 'descriptor_name': 'Electron Transport', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D006873', 'descriptor_name': 'Hydroquinones', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}, {'descriptor_ui': 'D010084', 'descriptor_name': 'Oxidation-Reduction', 'qualifier_ui': '', 'qualifier_name': None, 'is_major_topic': False}], 'locations_count': 2, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/ja308700t', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S111155417', 'display_name': 'Journal of the American Chemical Society', 'issn_l': '0002-7863', 'issn': ['0002-7863', '1520-5126', '1943-2984'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/23113818', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'id': 'https://metadata.un.org/sdg/6', 'display_name': 'Clean water and sanitation', 'score': 0.86}], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 39, 'referenced_works': ['https://openalex.org/W1520399805', 'https://openalex.org/W1907714540', 'https://openalex.org/W1979112715', 'https://openalex.org/W1983731372', 'https://openalex.org/W1986108540', 'https://openalex.org/W1995067163', 'https://openalex.org/W2000738543', 'https://openalex.org/W2009414976', 'https://openalex.org/W2019564570', 'https://openalex.org/W2019692171', 'https://openalex.org/W2023125456', 'https://openalex.org/W2024763149', 'https://openalex.org/W2029615583', 'https://openalex.org/W2032839609', 'https://openalex.org/W2034259337', 'https://openalex.org/W2041930594', 'https://openalex.org/W2049822774', 'https://openalex.org/W2053288121', 'https://openalex.org/W2058925597', 'https://openalex.org/W2061742480', 'https://openalex.org/W2073619962', 'https://openalex.org/W2075492091', 'https://openalex.org/W2075610716', 'https://openalex.org/W2084453454', 'https://openalex.org/W2088079252', 'https://openalex.org/W2092182400', 'https://openalex.org/W2099361743', 'https://openalex.org/W2121243460', 'https://openalex.org/W2131668520', 'https://openalex.org/W2143443903', 'https://openalex.org/W2148692463', 'https://openalex.org/W2161929344', 'https://openalex.org/W2314693860', 'https://openalex.org/W2320302983', 'https://openalex.org/W2329515784', 'https://openalex.org/W2950072741', 'https://openalex.org/W4211091797', 'https://openalex.org/W4376546076', 'https://openalex.org/W71721065'], 'related_works': ['https://openalex.org/W782822781', 'https://openalex.org/W4394568308', 'https://openalex.org/W4254331044', 'https://openalex.org/W2085585736', 'https://openalex.org/W2033715726', 'https://openalex.org/W2000884029', 'https://openalex.org/W1979048776', 'https://openalex.org/W1971223848', 'https://openalex.org/W1920995421', 'https://openalex.org/W1856585212'], 'abstract_inverted_index': {'Benzoquinone/hydroquinone': [0], 'redox': [1], 'interconversion': [2], 'by': [3], 'the': [4, 20, 38, 59], 'reversible': [5], 'Os(dmb)33+/2+': [6], 'couple': [7], 'over': [8], 'an': [9], 'extended': [10], 'pH': [11], 'range': [12], 'with': [13, 30], 'added': [14], 'acids': [15], 'and': [16, 51, 56, 66], 'bases': [17], 'has': [18, 33], 'revealed': [19, 45], 'existence': [21], 'of': [22, 27, 40, 64, 68], 'seven': [23], 'discrete': [24], 'pathways.': [25], 'Application': [26], 'spectrophotometric': [28], 'monitoring': [29], 'stopped-flow': [31], 'mixing': [32], 'been': [34], 'used': [35], 'to': [36], 'explore': [37], 'role': [39, 47], 'PCET.': [41], 'The': [42], 'results': [43], 'have': [44], 'a': [46], 'for': [48], 'phosphoric': [49], 'acid': [50], 'acetate': [52], 'as': [53], 'proton': [54], 'donor': [55], 'acceptor': [57], 'in': [58], 'concerted': [60], 'electron–proton': [61], 'transfer': [62], 'reduction': [63], 'benzoquinone': [65], 'oxidation': [67], 'hydroquinone,': [69], 'respectively.': [70]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2092710284', 'counts_by_year': [{'year': 2024, 'cited_by_count': 3}, {'year': 2023, 'cited_by_count': 5}, {'year': 2022, 'cited_by_count': 6}, {'year': 2021, 'cited_by_count': 3}, {'year': 2020, 'cited_by_count': 1}, {'year': 2019, 'cited_by_count': 5}, {'year': 2018, 'cited_by_count': 6}, {'year': 2017, 'cited_by_count': 5}, {'year': 2016, 'cited_by_count': 6}, {'year': 2015, 'cited_by_count': 2}, {'year': 2014, 'cited_by_count': 6}, {'year': 2013, 'cited_by_count': 4}], 'updated_date': '2024-09-19T01:00:35.363990', 'created_date': '2016-06-24'}