Title: The Development of Enantioselective Rhodium-Catalysed Hydroboration of Olefins
Abstract: Advanced Synthesis & CatalysisVolume 347, Issue 5 p. 609-631 Review The Development of Enantioselective Rhodium-Catalysed Hydroboration of Olefins Anne-Marie Carroll, Anne-Marie Carroll Centre for Synthesis and Chemical Biology, Conway Institute of Biomolecular and Biomedical Research, Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland, Fax: (+353)-1-716-6701Search for more papers by this authorTimothy P. O'Sullivan, Timothy P. O'Sullivan Centre for Synthesis and Chemical Biology, Conway Institute of Biomolecular and Biomedical Research, Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland, Fax: (+353)-1-716-6701Search for more papers by this authorPatrick J. Guiry, Patrick J. Guiry [email protected] Centre for Synthesis and Chemical Biology, Conway Institute of Biomolecular and Biomedical Research, Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland, Fax: (+353)-1-716-6701Search for more papers by this author Anne-Marie Carroll, Anne-Marie Carroll Centre for Synthesis and Chemical Biology, Conway Institute of Biomolecular and Biomedical Research, Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland, Fax: (+353)-1-716-6701Search for more papers by this authorTimothy P. O'Sullivan, Timothy P. O'Sullivan Centre for Synthesis and Chemical Biology, Conway Institute of Biomolecular and Biomedical Research, Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland, Fax: (+353)-1-716-6701Search for more papers by this authorPatrick J. Guiry, Patrick J. Guiry [email protected] Centre for Synthesis and Chemical Biology, Conway Institute of Biomolecular and Biomedical Research, Department of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland, Fax: (+353)-1-716-6701Search for more papers by this author First published: 08 April 2005 https://doi.org/10.1002/adsc.200404232Citations: 302AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract Rhodium-catalysed enantioselective hydroboration of olefins is a valuable synthetic transformation, typically employing a chiral catalyst and an achiral borane source. The pertinent chemo-, regio- and enantioselectivity issues of this reaction are discussed. However, the main emphasis of this review is on the evolution of catalytic asymmetric hydroboration. This has primarily relied upon the development and application of chiral bidentate P,P and P,N ligands which have exhibited varying degrees of success in this transformation. References 1 H. C. Brown, B. C. Subba Rao, J. Am. Chem. Soc. 1956, 78, 2582. 2 I. Beletskaya, A. Pelter, Tetrahedron 1997, 53, 4957. 3 C. E. Tucker, J. Davidson, P. Knochel, J. Org. Chem. 1992, 57, 3482. 4 H. Kono, K. Ito, Y. Nagai, Chem. Lett. 1975, 1095. 5 S. A. Westcott, N. J. Taylor, T. B. Marder, R. T. Baker, N. L. Jones, J. C. Calabrese, J. Chem. Soc. Chem. 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Publication Year: 2005
Publication Date: 2005-04-01
Language: en
Type: article
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