Title: Cobalt and tantalum additions for enhanced electrochromic performances of nickel-based oxide thin films grown by pulsed laser deposition
Abstract: Aiming at improving the durability of anodic electrochromic nickel oxide thin films, Ni–M–O (M = Co, Ta) thin films were grown by pulsed laser deposition (PLD), using optimized conditions, namely room temperature and 10−1 mbar oxygen pressure. For low Co and Ta contents (<5%), both additions lead to a loss of the [1 1 1] preferred orientation of the NiO rock-salt structure followed by a film amorphization with increasing Ta amount. Among the two series of metal additions (M ≤ 20%), the Ni–Co–O (5% Co) and Ni–Ta–O (10% Ta) thin films show the highest electrochemical performances especially in respect of improved durability. If the enhanced properties are associated with a limited dissolution of the oxidized phase for the Ni–Ta–O system, the opposite trend is observed for the Ni–Co–O system as compared to pure NiO.
Publication Year: 2005
Publication Date: 2005-11-22
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 31
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