Title: Old Molecules, New Concepts: [Ru(bpy)<sub>3</sub>]<sup>2+</sup> as a Molecular Encoder–Decoder
Abstract: Angewandte Chemie International EditionVolume 48, Issue 45 p. 8516-8518 Communication Old Molecules, New Concepts: [Ru(bpy)3]2+ as a Molecular Encoder–Decoder† Paola Ceroni Prof., Paola Ceroni Prof. Department of Chemistry "G. Ciamician", University of Bologna via Selmi 2, 40126 Bologna (Italy)Search for more papers by this authorGiacomo Bergamini Dr., Giacomo Bergamini Dr. Department of Chemistry "G. Ciamician", University of Bologna via Selmi 2, 40126 Bologna (Italy)Search for more papers by this authorVincenzo Balzani Prof., Vincenzo Balzani Prof. [email protected] Department of Chemistry "G. Ciamician", University of Bologna via Selmi 2, 40126 Bologna (Italy)Search for more papers by this author Paola Ceroni Prof., Paola Ceroni Prof. Department of Chemistry "G. Ciamician", University of Bologna via Selmi 2, 40126 Bologna (Italy)Search for more papers by this authorGiacomo Bergamini Dr., Giacomo Bergamini Dr. Department of Chemistry "G. Ciamician", University of Bologna via Selmi 2, 40126 Bologna (Italy)Search for more papers by this authorVincenzo Balzani Prof., Vincenzo Balzani Prof. [email protected] Department of Chemistry "G. Ciamician", University of Bologna via Selmi 2, 40126 Bologna (Italy)Search for more papers by this author First published: 20 October 2009 https://doi.org/10.1002/anie.200904764Citations: 127 † This work was supported by Fondazione Carisbo "Dispositivi nanometrici". bpy=2,2′-bipyridine. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Totally logical: The well-known complex [Ru(bpy)3]2+ (bpy=2,2′-bipyridine) can perform as both a 4-to-2 encoder and a 2-to-4 decoder (see picture; gray C, blue N, red Ru) by a combination of electronic and photonic inputs and outputs. The system can be reset in situ without the addition of chemical reagents. This approach is considered as an alternative route to solid-state molecular electronics and the design and construction of chemical computers. References 1R. Breslow, Chemistry Today and Tomorrow, American Chemical Society, Washington, DC, 1997. 2V. Balzani, A. Credi, M. Venturi, Chem. Eur. J. 2008, 14, 26– 39. 3aJ.-M. Lehn, Chem. Soc. Rev. 2007, 36, 151; 3bJ.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH, Weinheim, 1995. 4A. P. De Silva, S. Uchiyama, Nat. Nanotechnol. 2007, 2, 399– 410. 5K. S. Chichak, S. J. Cantrill, A. R. Pease, S.-H. Chiu, G. W. V. Cave, J. L. Atwood, J. F. 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Publication Year: 2009
Publication Date: 2009-10-20
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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