Title: Stereochemical applications of mass spectrometry: 1—The utility of electron impact and chemical ionization mass spectrometry in the differentiation of stereoisomeric benzoin oximes and phenylhydrazones
Abstract: Abstract A study of the electron impact and chemical ionization (H 2 , CH 4 , and iso‐C 4 H 10 ) mass spectra of stereoisomeric benzoin oximes and phenylhydrazones indicates that while the former can be distinguished only by their chemical ionization mass spectra the latter are readily distinguishable by both their electron impact and chemical ionization mass spectra. The electron impact mass spectra of the isomeric oximes are practically identical; however, the chemical ionization spectra show that the E isomer forms more stable [MH] + and [MHH 2 O] + ions than the Z isomer for which both the [MH] + and [MHH 2 O] + ions are relatively unstable. In electron impact the Z ‐phenylhydrazone shows a lower [M] + ˙ ion abundance and more facile loss of H 2 O than does the E isomer. This more facile H 2 O loss also is observed for the [MH] + ion of the Z isomer under chemical ionization conditions.
Publication Year: 1980
Publication Date: 1980-05-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 17
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot