The Thermal Decomposition of Cyanodiphenylmethyl<i>t</i>-Butyl Peroxide An Example of C–O Bond Scission

Name: Work Video:
Duration: 3 min 30 s
Description: The thermal decomposition of cyanodiphenylmethyl t-butyl peroxide was investigated. The peroxide is abnormally stable and decomposes slowly at 130–135 °C, and the main reaction product is tetraphenylsuccinonitrile. A main reaction path including the C–O bond scission, in contrast to the case of triphenylmethyl t-butyl peroxide, is proposed.
Masao Ōkubo; Emiko Iba-Imai; Hiroko Mizuta; Takumi Kawamoto
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