Hydrotris(3-mesitylpyrazolyl)borato-copper(i) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts

Name: Work Video:
Duration: 3 min 30 s
Carmen Martín; M. Sierra; Eleuterio Álvarez; Tomás R. Belderraín; Pedro J. Pérez
{'id': 'https://openalex.org/W2079162176', 'doi': 'https://doi.org/10.1039/c2dt11951j', 'title': 'Hydrotris(3-mesitylpyrazolyl)borato-copper(i) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts', 'display_name': 'Hydrotris(3-mesitylpyrazolyl)borato-copper(i) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts', 'publication_year': 2012, 'publication_date': '2012-01-01', 'ids': {'openalex': 'https://openalex.org/W2079162176', 'doi': 'https://doi.org/10.1039/c2dt11951j', 'mag': '2079162176', 'pmid': 'https://pubmed.ncbi.nlm.nih.gov/22382395'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1039/c2dt11951j', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S166159787', 'display_name': 'Dalton Transactions', 'issn_l': '1477-9226', 'issn': ['1477-9226', '1477-9234'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref', 'pubmed'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5085237962', 'display_name': 'Carmen Martín', 'orcid': 'https://orcid.org/0000-0001-8687-6887'}, 'institutions': [{'id': 'https://openalex.org/I78880903', 'display_name': 'Universidad de Huelva', 'ror': 'https://ror.org/03a1kt624', 'country_code': 'ES', 'type': 'education', 'lineage': ['https://openalex.org/I78880903']}], 'countries': ['ES'], 'is_corresponding': False, 'raw_author_name': 'Carmen Martín', 'raw_affiliation_strings': ['Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain'], 'affiliations': [{'raw_affiliation_string': 'Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain', 'institution_ids': ['https://openalex.org/I78880903']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5065162748', 'display_name': 'M. Sierra', 'orcid': 'https://orcid.org/0000-0002-1738-4392'}, 'institutions': [{'id': 'https://openalex.org/I78880903', 'display_name': 'Universidad de Huelva', 'ror': 'https://ror.org/03a1kt624', 'country_code': 'ES', 'type': 'education', 'lineage': ['https://openalex.org/I78880903']}], 'countries': ['ES'], 'is_corresponding': False, 'raw_author_name': 'Marta Sierra', 'raw_affiliation_strings': ['Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain'], 'affiliations': [{'raw_affiliation_string': 'Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain', 'institution_ids': ['https://openalex.org/I78880903']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5078170195', 'display_name': 'Eleuterio Álvarez', 'orcid': 'https://orcid.org/0000-0002-8378-8459'}, 'institutions': [{'id': 'https://openalex.org/I79238269', 'display_name': 'Universidad de Sevilla', 'ror': 'https://ror.org/03yxnpp24', 'country_code': 'ES', 'type': 'education', 'lineage': ['https://openalex.org/I79238269']}], 'countries': ['ES'], 'is_corresponding': False, 'raw_author_name': 'Eleuterio Alvarez', 'raw_affiliation_strings': ['Instituto de Investigaciones Químicas, CSIC-Universidad de Sevilla, Avenida Américo Vespucio 49, 41092-Sevilla, Spain'], 'affiliations': [{'raw_affiliation_string': 'Instituto de Investigaciones Químicas, CSIC-Universidad de Sevilla, Avenida Américo Vespucio 49, 41092-Sevilla, Spain', 'institution_ids': ['https://openalex.org/I79238269']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5070638043', 'display_name': 'Tomás R. Belderraín', 'orcid': 'https://orcid.org/0000-0003-2839-1050'}, 'institutions': [{'id': 'https://openalex.org/I78880903', 'display_name': 'Universidad de Huelva', 'ror': 'https://ror.org/03a1kt624', 'country_code': 'ES', 'type': 'education', 'lineage': ['https://openalex.org/I78880903']}], 'countries': ['ES'], 'is_corresponding': False, 'raw_author_name': 'Tomás R. Belderrain', 'raw_affiliation_strings': ['Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain'], 'affiliations': [{'raw_affiliation_string': 'Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain', 'institution_ids': ['https://openalex.org/I78880903']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5045676433', 'display_name': 'Pedro J. Pérez', 'orcid': 'https://orcid.org/0000-0002-6899-4641'}, 'institutions': [{'id': 'https://openalex.org/I78880903', 'display_name': 'Universidad de Huelva', 'ror': 'https://ror.org/03a1kt624', 'country_code': 'ES', 'type': 'education', 'lineage': ['https://openalex.org/I78880903']}], 'countries': ['ES'], 'is_corresponding': False, 'raw_author_name': 'Pedro J. Pérez', 'raw_affiliation_strings': ['Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain'], 'affiliations': [{'raw_affiliation_string': 'Laboratorio de Catálisis Homogénea, Departamento de Química y Ciencia de los Materiales, Unidad Asociada al CSIC, Centro de Investigación en Química Sostenible (CIQSO), Universidad de Huelva, Campus de El Carmen, 21007-Huelva, Spain', 'institution_ids': ['https://openalex.org/I78880903']}]}], 'institution_assertions': [], 'countries_distinct_count': 1, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 0.742, 'has_fulltext': True, 'fulltext_origin': 'pdf', 'cited_by_count': 24, 'citation_normalized_percentile': {'value': 0.860296, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 91, 'max': 92}, 'biblio': {'volume': '41', 'issue': '17', 'first_page': '5319', 'last_page': '5319'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T11611', 'display_name': 'Cyclopropane Reaction Mechanisms', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T11611', 'display_name': 'Cyclopropane Reaction Mechanisms', 'score': 0.9997, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9986, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10871', 'display_name': 'Catalytic Alkyne Reactions', 'score': 0.9976, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/alkyne', 'display_name': 'Alkyne', 'score': 0.99234104}, {'id': 'https://openalex.org/keywords/phenylacetylene', 'display_name': 'Phenylacetylene', 'score': 0.6489836}, {'id': 'https://openalex.org/keywords/reactivity', 'display_name': 'Reactivity', 'score': 0.58754635}, {'id': 'https://openalex.org/keywords/diphenylacetylene', 'display_name': 'Diphenylacetylene', 'score': 0.41430607}], 'concepts': [{'id': 'https://openalex.org/C2779012754', 'wikidata': 'https://www.wikidata.org/wiki/Q159226', 'display_name': 'Alkyne', 'level': 3, 'score': 0.99234104}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.69505715}, {'id': 'https://openalex.org/C2778545935', 'wikidata': 'https://www.wikidata.org/wiki/Q417321', 'display_name': 'Phenylacetylene', 'level': 3, 'score': 0.6489836}, {'id': 'https://openalex.org/C2776910235', 'wikidata': 'https://www.wikidata.org/wiki/Q18574', 'display_name': 'Reactivity (psychology)', 'level': 3, 'score': 0.58754635}, {'id': 'https://openalex.org/C108204754', 'wikidata': 'https://www.wikidata.org/wiki/Q353392', 'display_name': 'Adduct', 'level': 2, 'score': 0.56057525}, {'id': 'https://openalex.org/C161790260', 'wikidata': 'https://www.wikidata.org/wiki/Q82264', 'display_name': 'Catalysis', 'level': 2, 'score': 0.48758906}, {'id': 'https://openalex.org/C544778455', 'wikidata': 'https://www.wikidata.org/wiki/Q753', 'display_name': 'Copper', 'level': 2, 'score': 0.4845566}, {'id': 'https://openalex.org/C116569031', 'wikidata': 'https://www.wikidata.org/wiki/Q899107', 'display_name': 'Ligand (biochemistry)', 'level': 3, 'score': 0.46077177}, {'id': 'https://openalex.org/C155647269', 'wikidata': 'https://www.wikidata.org/wiki/Q243455', 'display_name': 'Medicinal chemistry', 'level': 1, 'score': 0.42788482}, {'id': 'https://openalex.org/C2781019423', 'wikidata': 'https://www.wikidata.org/wiki/Q902100', 'display_name': 'Diphenylacetylene', 'level': 3, 'score': 0.41430607}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.35101143}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.21963763}, {'id': 'https://openalex.org/C170493617', 'wikidata': 'https://www.wikidata.org/wiki/Q208467', 'display_name': 'Receptor', 'level': 2, 'score': 0.0668388}, {'id': 'https://openalex.org/C142724271', 'wikidata': 'https://www.wikidata.org/wiki/Q7208', 'display_name': 'Pathology', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C71924100', 'wikidata': 'https://www.wikidata.org/wiki/Q11190', 'display_name': 'Medicine', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C55493867', 'wikidata': 'https://www.wikidata.org/wiki/Q7094', 'display_name': 'Biochemistry', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C204787440', 'wikidata': 'https://www.wikidata.org/wiki/Q188504', 'display_name': 'Alternative medicine', 'level': 2, 'score': 0.0}], 'mesh': [], 'locations_count': 2, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1039/c2dt11951j', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S166159787', 'display_name': 'Dalton Transactions', 'issn_l': '1477-9226', 'issn': ['1477-9226', '1477-9234'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320556', 'host_organization_name': 'Royal Society of Chemistry', 'host_organization_lineage': ['https://openalex.org/P4310320556'], 'host_organization_lineage_names': ['Royal Society of Chemistry'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, {'is_oa': False, 'landing_page_url': 'https://pubmed.ncbi.nlm.nih.gov/22382395', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4306525036', 'display_name': 'PubMed', 'issn_l': None, 'issn': None, 'is_oa': False, 'is_in_doaj': False, 'is_core': False, 'host_organization': 'https://openalex.org/I1299303238', 'host_organization_name': 'National Institutes of Health', 'host_organization_lineage': ['https://openalex.org/I1299303238'], 'host_organization_lineage_names': ['National Institutes of Health'], 'type': 'repository'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [{'display_name': 'Clean water and sanitation', 'id': 'https://metadata.un.org/sdg/6', 'score': 0.47}], 'grants': [], 'datasets': ['https://openalex.org/W4398062193', 'https://openalex.org/W4398122354', 'https://openalex.org/W4398129231'], 'versions': [], 'referenced_works_count': 39, 'referenced_works': ['https://openalex.org/W1967310757', 'https://openalex.org/W1972675337', 'https://openalex.org/W1974423375', 'https://openalex.org/W1986720649', 'https://openalex.org/W1990395841', 'https://openalex.org/W1995562640', 'https://openalex.org/W1999233351', 'https://openalex.org/W2003299011', 'https://openalex.org/W2006998595', 'https://openalex.org/W2014175605', 'https://openalex.org/W2014888479', 'https://openalex.org/W2016590816', 'https://openalex.org/W2017347157', 'https://openalex.org/W2020954166', 'https://openalex.org/W2023557482', 'https://openalex.org/W2030249400', 'https://openalex.org/W2031781571', 'https://openalex.org/W2035840517', 'https://openalex.org/W2039311917', 'https://openalex.org/W2049031448', 'https://openalex.org/W2049249446', 'https://openalex.org/W2058988554', 'https://openalex.org/W2060903578', 'https://openalex.org/W2063151067', 'https://openalex.org/W2064075877', 'https://openalex.org/W2064141912', 'https://openalex.org/W2066370105', 'https://openalex.org/W2078868481', 'https://openalex.org/W2080408960', 'https://openalex.org/W2088309473', 'https://openalex.org/W2095440822', 'https://openalex.org/W2121216877', 'https://openalex.org/W2168872924', 'https://openalex.org/W2334525169', 'https://openalex.org/W2527132417', 'https://openalex.org/W2942220698', 'https://openalex.org/W2942837424', 'https://openalex.org/W2949604916', 'https://openalex.org/W3136633314'], 'related_works': ['https://openalex.org/W2952896926', 'https://openalex.org/W2952726746', 'https://openalex.org/W2951014079', 'https://openalex.org/W2317358861', 'https://openalex.org/W2169368326', 'https://openalex.org/W2156174565', 'https://openalex.org/W2078242443', 'https://openalex.org/W2057297118', 'https://openalex.org/W2020215802', 'https://openalex.org/W1990293661'], 'abstract_inverted_index': {'The': [0, 26], 'use': [1], 'of': [2, 12, 31, 44], 'the': [3, 10, 42, 50, 54, 77, 85], 'bulky': [4], 'hydrotris(3-mesitylpyrazolyl)borate': [5], 'anionic': [6], 'ligand': [7], 'has': [8], 'allowed': [9], 'synthesis': [11], 'stable': [13, 67], 'TpMsCu(alkyne)': [14], 'complexes': [15, 87], '(alkyne': [16], '=': [17], '1-hexyne,': [18], '1,': [19], 'phenylacetylene,': [20], '2,': [21], 'and': [22, 28, 34, 91], 'ethyl': [23], 'propiolate,': [24], '3).': [25], 'spectroscopic': [27], 'structural': [29], 'features': [30], 'these': [32], 'compounds': [33], 'their': [35, 94], 'relative': [36, 95], 'reactivity': [37], 'have': [38, 59], 'been': [39], 'examined,': [40], 'indicating': [41], 'existence': [43], 'a': [45], 'low': [46], 'π': [47], 'back-bonding': [48], 'from': [49], 'copper(I)': [51], 'centre': [52], 'to': [53], 'alkyne.': [55], 'Ligand': [56], 'exchange': [57], 'experiments': [58], 'shown': [60], 'that': [61], 'terminal': [62], 'alkyne': [63, 70, 80], 'adducts': [64], 'are': [65], 'more': [66], 'than': [68], 'internal': [69], 'analogues.': [71], 'In': [72], 'good': [73], 'accordance': [74], 'with': [75, 93], 'this,': [76], 'previously': [78], 'reported': [79], 'cyclopropenation': [81], 'reaction': [82], 'catalysed': [83], 'by': [84], 'TpxCu': [86], 'can': [88], 'be': [89], 'rationalized': [90], 'correlated': [92], 'stability.': [96]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2079162176', 'counts_by_year': [{'year': 2022, 'cited_by_count': 2}, {'year': 2021, 'cited_by_count': 3}, {'year': 2020, 'cited_by_count': 2}, {'year': 2019, 'cited_by_count': 3}, {'year': 2018, 'cited_by_count': 2}, {'year': 2017, 'cited_by_count': 1}, {'year': 2016, 'cited_by_count': 6}, {'year': 2015, 'cited_by_count': 1}, {'year': 2014, 'cited_by_count': 1}, {'year': 2013, 'cited_by_count': 2}, {'year': 2012, 'cited_by_count': 1}], 'updated_date': '2025-01-11T02:57:00.938737', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
