Title: Synthetic, spectroscopic and structural studies of two novel phosphanyl(organyl)borane compounds
Abstract: The titanium (II) complex, Cp2Ti(HBcat)2, catalyzes the hydroboration of diphenylvinylphosphine by catecholborane and pinacolborane to afford exclusive anti-Markovnikov phosphanyl(organyl)boranes cleanly, rapidly and in good yields. Spectroscopic and X-ray studies of the phosphanyl(organyl)borane products show no evidence of boron–phosphorus interaction, indicating that the compounds preclude formation of Lewis pairs.
Publication Year: 2008
Publication Date: 2008-02-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 17
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