Title: Chemiluminescent reaction of oxygen atoms with dimethyl disulfide and dimethyl sulfide
Abstract: Broad chemiluminescence spectra in the range 240–460 nm with a sharp peak at 308.5 nm are obtained from the reaction between oxygen atoms [O(3P)] with dimethyl disulfide (DMDS) and dimethyl sulfide (DMS). The emitting species are identified as OH (A2Σ+) and SO2(3B, 1B). The photon yields are found to be 3.3 × 10–6 and 4.4 × 10–6 for DMDS and DMS, respectively. Computer simulations were carried out to elucidate the reaction mechanism.
Publication Year: 1994
Publication Date: 1994-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 2
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