Title: Thermal studies of ‘dialkyldioxouranium(VI)’
Abstract: Dichlorodioxouranium(VI) reacts with RLi or RMgCl (R = hydrocarbyl) in polar and nonpolar solvents to form (presumably) the thermally unstable 'UO2R2' species, which upon warming to room temperature either 1) reductively eliminates RR leaving UO2 (R = phenyl), or 2) decomposes by β-hydride elimination to give the corresponding alkane and alkene and UO2, (when R = i-propyl, n-butyl, and t-butyl), or 3) affords the corresponding alkane (R = methyl) or alkene (R ] vinyl) via hydrogen abstraction. Microanalysis, and spectroscopic and gas chromatographic data are discussed.
Publication Year: 1982
Publication Date: 1982-01-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 28
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot