Title: Electrochemical Behaviour of Dissolved Iron Chloride in KCl+LiCl+NaCl Melt at 550ºC
Abstract:An electrochemical study of iron was carried out in KCl+LiCl+NaCl melt at 550ºC using a glassy carbon working electrode. Cyclic voltammetry showed that the Fe(II)/Fe(0) electron exchange is a soluble/...An electrochemical study of iron was carried out in KCl+LiCl+NaCl melt at 550ºC using a glassy carbon working electrode. Cyclic voltammetry showed that the Fe(II)/Fe(0) electron exchange is a soluble/insoluble reversible process. The diffusion coefficient of Fe(II) was calculated using cyclic voltammetry; 1.4×10 -5 cm 2 s -1 . For the Fe(II)/Fe(III) red/ox reaction, analysis of the voltammograms suggests that the process is not reversible and is coupled with a chemical reaction. The stability of FeCl 3 and the effect of equilibrium between FeCl 3 and FeCl 2 are also briefly discussed.Read More