Abstract: The melting curve of NaClO3 initially increases with pressure and reaches a maximum at 6 kbar and 285°C. A very slight break in the curve at 8.2 kbar and 282°C may indicate the NaClO3 I—II—liquid triple point and is in reasonable agreement with the extrapolation of Bridgman's I—II boundary. The melting curve further decreases with pressure and meets Bridgman's II—III boundary in a triple point at 31 kbar and 100°C. Bridgman's NaClO3 IV is actually the liquid phase. The freezing of NaClO3 exhibits considerable supercooling at high pressure, and above 20 kbar liquid NaClO3 appears to be very viscous and behaves like a glass.
Publication Year: 1967
Publication Date: 1967-05-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 16
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