Title: A Biomimetic Transformation of Serratinine into Serratezomine A through a Modified Polonovski Reaction
Abstract: Application of a modified Polonovski reaction for serratinine (1) resulted in generation of serratezomine A (2) with a novel seco-serratinine-type skeleton recently isolated from the club moss Lycopodium serratum var. serratum. This biomimetic transformation supports a biogenetic pathway proposed for serratezomine A (2). The absolute stereochemistry of serratezomine A (2) was established by an induced exciton chirality and modified Mosher methods.
Publication Year: 2002
Publication Date: 2002-06-25
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 33
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