Title: Preparation of Ir<sub>4</sub>(CO)<sub>12</sub>and Rh<sub>6</sub>(CO)<sub>16</sub>from the Reductive Carbonylation of Iridium(I) and Rhodium(I) 1,5-Cyclooctadiene Compounds
Abstract:Abstract The iridium(O) carbonyl cluster, Ir4(CO)12 (1), and rhodium(O) carbonyl cluster, Rh6(CO)16 (2), were prepared from the reactions of [Ir(COD)(PhCN)2]BF4 (3) and [Rh(COD)(PhCN)2]BF4 (4) (COD = ...Abstract The iridium(O) carbonyl cluster, Ir4(CO)12 (1), and rhodium(O) carbonyl cluster, Rh6(CO)16 (2), were prepared from the reactions of [Ir(COD)(PhCN)2]BF4 (3) and [Rh(COD)(PhCN)2]BF4 (4) (COD = 1,5-cyclooctadiene) with CO (2 atm) and H2 (7 atm) at 100 °C in high yield (>95 %).Read More
Publication Year: 1995
Publication Date: 1995-03-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 2
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