Title: The Formal Oxidation States of Iridium Now Run from −III to +IX
Abstract: Angewandte Chemie International EditionVolume 54, Issue 4 p. 1080-1081 Highlight The Formal Oxidation States of Iridium Now Run from −III to +IX† Prof. Dr. Pekka Pyykkö, Corresponding Author Prof. Dr. Pekka Pyykkö [email protected] Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)Search for more papers by this authorDr. Wen-Hua Xu, Dr. Wen-Hua Xu Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland) Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, 710127 Xi'an (China)Search for more papers by this author Prof. Dr. Pekka Pyykkö, Corresponding Author Prof. Dr. Pekka Pyykkö [email protected] Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)Search for more papers by this authorDr. Wen-Hua Xu, Dr. Wen-Hua Xu Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland) Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, 710127 Xi'an (China)Search for more papers by this author First published: 16 December 2014 https://doi.org/10.1002/anie.201410615Citations: 25 † We thank Prof. Dage Sundholm for organizing the support from The Academy of Finland (Project 275845) for W.-H.X. at Helsinki and the Northwest University, Xi'an for a leave of absence. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Rarer than a new element: Recently Wang et al. produced the [(Ir+IX)O4]+ ion by a pulsed laser vaporization/thermal expansion method and studied it by IR photodissociation spectroscopy. The oxidation state of +IX had been unknown previously. The picture shows the mass spectra for the argon-tagged iridium oxide species. References 1G.-J. Wang, M.-F. Zhou, J. T. Goettel, G. J. Schrobilgen, J. Su, J. Li, T. Schlöder, S. Riedel, Nature 2014, 514, 475– 478. 2J. M. Allen, W. W. Brennessel, C. E. Buss, J. E. Ellis, M. E. Minyaev, M. Pink, G. F. Warnock, M. L. Winzenburg, V. G. Young, Jr., Inorg. Chem. 2001, 40, 5279– 5284. 3Y. T. Oganessian, F. S. Abdullin, P. D. Bailey, D. E. Benker, M. E. Bennett, S. N. Dmitriev, J. G. Ezold, J. H. Hamilton, R. A. Henderson, M. G. Itkis, Y. V. Lobanov, A. N. Mezentsev, K. J. Moody, S. L. Nelson, A. N. Polyakov, C. E. Porter, A. Ramayya, F. D. Riley, J. B. Roberto, M. A. Ryabinin, K. P. Rykaczewski, R. N. Sagaidak, D. A. Shaughnessy, I. Shirokovsky, M. A. Stoyer, V. G. Subbotin, R. Sudowe, A. M. Sukhov, Y. S. Tsyganov, V. K. Utyonkov, A. A. Voinov, G. K. Vostokin, P. A. Wilk, Phys. Rev. Lett. 2010, 104, 142502. 4A. Karpov, J. Nuss, U. Wedig, M. Jansen, Angew. Chem. Int. Ed. 2003, 42, 4818– 4821; Angew. Chem. 2003, 115, 4966– 4969. 5C. H. L. Goodman, J. Phys. Chem. Solids 1958, 6, 305– 314. 6P. Pyykkö, Angew. Chem. Int. Ed. 2002, 41, 3573– 3578; Angew. Chem. 2002, 114, 3723– 3728. 7P. Pyykkö, Phys. Chem. Chem. Phys. 2012, 14, 14734– 14742. 8P. Pyykkö, J. Organomet. Chem. 2006, 691, 4336– 4340. 9J. E. Ellis, Inorg. Chem. 2006, 45, 3167– 3186. 10W. T. K. Chan, W. T. Wong, Polyhedron 2013, 52, 43– 61. 11P. Pyykkö, Angew. Chem. Int. Ed. 2004, 43, 4412– 4456; Angew. Chem. 2004, 116, 4512– 4557. 12Y. Gong, M.-F. Zhou, M. Kaupp, S. Riedel, Angew. Chem. Int. Ed. 2009, 48, 7879– 7883; Angew. Chem. 2009, 121, 8019– 8023. 13D. Himmel, C. Knapp, M. Patzschke, S. Riedel, ChemPhysChem 2010, 11, 865– 869. See also [15]. 14S. Ritter, Chem. Eng. News 2014, 92( 43), 7. 15A. I. Dement′ev, M. L. Kuznetsov, Y. M. Kiselev, Russian J. Inorg. Chem. 1997, 42, 1052– 1057; A. I. Dement′ev, M. L. Kuznetsov, Y. M. Kiselev, Zh. Neorg. Khim. 1997, 42, 1167– 1172. Citing Literature Volume54, Issue4January 19, 2015Pages 1080-1081 ReferencesRelatedInformation
Publication Year: 2014
Publication Date: 2014-12-16
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 27
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