Title: Autoxidation of 2α-hydroxy-5α-cholestan-3-one in methanolic potassium hydroxide
Abstract:2α-Acetoxy-5α-cholestan-3-one in methanolic potassium hydroxide or in an excess of methanolic potassium carbonate at 20° for 16 hours is converted into a mixture of the monomethyl esters of 2,3-seco-5...2α-Acetoxy-5α-cholestan-3-one in methanolic potassium hydroxide or in an excess of methanolic potassium carbonate at 20° for 16 hours is converted into a mixture of the monomethyl esters of 2,3-seco-5α-cholestane-2,3-dicarboxylic acid. 5α-Cholestane-2,3-dione is isolated as an intermediate and is probably formed by autoxidation of 2α-hydroxy-5α-cholestan-3-one through 2-hydroperoxy-2-hydroxy-5α-cholestan-3-one.Read More
Publication Year: 1968
Publication Date: 1968-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 2
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