Crystal Structures of (+)-Sparteine Surrogate Adducts of Methyllithium and Phenyllithium

Name: Work Video:
Duration: 3 min 30 s
Carsten Strohmann; Katja Strohfeldt; D. Schildbach; Matthew J. McGrath; Peter O’Brien
{'id': 'https://openalex.org/W2061950648', 'doi': 'https://doi.org/10.1021/om0494871', 'title': 'Crystal Structures of (+)-Sparteine Surrogate Adducts of Methyllithium and Phenyllithium', 'display_name': 'Crystal Structures of (+)-Sparteine Surrogate Adducts of Methyllithium and Phenyllithium', 'publication_year': 2004, 'publication_date': '2004-10-07', 'ids': {'openalex': 'https://openalex.org/W2061950648', 'doi': 'https://doi.org/10.1021/om0494871', 'mag': '2061950648'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om0494871', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5033600382', 'display_name': 'Carsten Strohmann', 'orcid': 'https://orcid.org/0000-0002-4787-2135'}, 'institutions': [{'id': 'https://openalex.org/I52099693', 'display_name': 'University of York', 'ror': 'https://ror.org/04m01e293', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I52099693']}, {'id': 'https://openalex.org/I25974101', 'display_name': 'University of Würzburg', 'ror': 'https://ror.org/00fbnyb24', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I25974101']}], 'countries': ['DE', 'GB'], 'is_corresponding': False, 'raw_author_name': 'Carsten Strohmann', 'raw_affiliation_strings': ['Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD'], 'affiliations': [{'raw_affiliation_string': 'Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD', 'institution_ids': ['https://openalex.org/I52099693', 'https://openalex.org/I25974101']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5035701294', 'display_name': 'Katja Strohfeldt', 'orcid': 'https://orcid.org/0000-0002-0178-2425'}, 'institutions': [{'id': 'https://openalex.org/I25974101', 'display_name': 'University of Würzburg', 'ror': 'https://ror.org/00fbnyb24', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I25974101']}, {'id': 'https://openalex.org/I52099693', 'display_name': 'University of York', 'ror': 'https://ror.org/04m01e293', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I52099693']}], 'countries': ['DE', 'GB'], 'is_corresponding': False, 'raw_author_name': 'Katja Strohfeldt', 'raw_affiliation_strings': ['Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD'], 'affiliations': [{'raw_affiliation_string': 'Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD', 'institution_ids': ['https://openalex.org/I25974101', 'https://openalex.org/I52099693']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5032247505', 'display_name': 'D. Schildbach', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I25974101', 'display_name': 'University of Würzburg', 'ror': 'https://ror.org/00fbnyb24', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I25974101']}, {'id': 'https://openalex.org/I52099693', 'display_name': 'University of York', 'ror': 'https://ror.org/04m01e293', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I52099693']}], 'countries': ['DE', 'GB'], 'is_corresponding': False, 'raw_author_name': 'Daniel Schildbach', 'raw_affiliation_strings': ['Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD'], 'affiliations': [{'raw_affiliation_string': 'Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD', 'institution_ids': ['https://openalex.org/I25974101', 'https://openalex.org/I52099693']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5048384208', 'display_name': 'Matthew J. McGrath', 'orcid': 'https://orcid.org/0000-0003-3431-8466'}, 'institutions': [{'id': 'https://openalex.org/I25974101', 'display_name': 'University of Würzburg', 'ror': 'https://ror.org/00fbnyb24', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I25974101']}, {'id': 'https://openalex.org/I52099693', 'display_name': 'University of York', 'ror': 'https://ror.org/04m01e293', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I52099693']}], 'countries': ['DE', 'GB'], 'is_corresponding': False, 'raw_author_name': 'Matthew J. McGrath', 'raw_affiliation_strings': ['Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD'], 'affiliations': [{'raw_affiliation_string': 'Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD', 'institution_ids': ['https://openalex.org/I25974101', 'https://openalex.org/I52099693']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5074030394', 'display_name': 'Peter O’Brien', 'orcid': 'https://orcid.org/0000-0002-9966-1962'}, 'institutions': [{'id': 'https://openalex.org/I25974101', 'display_name': 'University of Würzburg', 'ror': 'https://ror.org/00fbnyb24', 'country_code': 'DE', 'type': 'education', 'lineage': ['https://openalex.org/I25974101']}, {'id': 'https://openalex.org/I52099693', 'display_name': 'University of York', 'ror': 'https://ror.org/04m01e293', 'country_code': 'GB', 'type': 'education', 'lineage': ['https://openalex.org/I52099693']}], 'countries': ['DE', 'GB'], 'is_corresponding': False, 'raw_author_name': "Peter O'Brien", 'raw_affiliation_strings': ['Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD'], 'affiliations': [{'raw_affiliation_string': 'Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, and Department of Chemistry, University of York, Heslington, York, U.K. YO10 5DD', 'institution_ids': ['https://openalex.org/I25974101', 'https://openalex.org/I52099693']}]}], 'institution_assertions': [], 'countries_distinct_count': 2, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': None, 'apc_paid': None, 'fwci': 4.551, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 62, 'citation_normalized_percentile': {'value': 0.829756, 'is_in_top_1_percent': False, 'is_in_top_10_percent': False}, 'cited_by_percentile_year': {'min': 94, 'max': 95}, 'biblio': {'volume': '23', 'issue': '23', 'first_page': '5389', 'last_page': '5391'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T12228', 'display_name': 'Coordination Chemistry and Organometallics', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T12228', 'display_name': 'Coordination Chemistry and Organometallics', 'score': 1.0, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10092', 'display_name': 'Organometallic Complex Synthesis and Catalysis', 'score': 0.9971, 'subfield': {'id': 'https://openalex.org/subfields/1605', 'display_name': 'Organic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T10807', 'display_name': 'Synthesis and characterization of novel inorganic/organometallic compounds', 'score': 0.9966, 'subfield': {'id': 'https://openalex.org/subfields/1604', 'display_name': 'Inorganic Chemistry'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/sparteine', 'display_name': 'Sparteine', 'score': 0.92925155}, {'id': 'https://openalex.org/keywords/methyllithium', 'display_name': 'Methyllithium', 'score': 0.879685}, {'id': 'https://openalex.org/keywords/phenyllithium', 'display_name': 'Phenyllithium', 'score': 0.7675844}], 'concepts': [{'id': 'https://openalex.org/C2778694420', 'wikidata': 'https://www.wikidata.org/wiki/Q419552', 'display_name': 'Sparteine', 'level': 2, 'score': 0.92925155}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.90436804}, {'id': 'https://openalex.org/C2779743861', 'wikidata': 'https://www.wikidata.org/wiki/Q413849', 'display_name': 'Methyllithium', 'level': 2, 'score': 0.879685}, {'id': 'https://openalex.org/C108204754', 'wikidata': 'https://www.wikidata.org/wiki/Q353392', 'display_name': 'Adduct', 'level': 2, 'score': 0.81845003}, {'id': 'https://openalex.org/C2777270887', 'wikidata': 'https://www.wikidata.org/wiki/Q419478', 'display_name': 'Phenyllithium', 'level': 2, 'score': 0.7675844}, {'id': 'https://openalex.org/C115624301', 'wikidata': 'https://www.wikidata.org/wiki/Q895901', 'display_name': 'Crystal structure', 'level': 2, 'score': 0.72343296}, {'id': 'https://openalex.org/C2779546866', 'wikidata': 'https://www.wikidata.org/wiki/Q531306', 'display_name': 'Dimer', 'level': 2, 'score': 0.71595746}, {'id': 'https://openalex.org/C71240020', 'wikidata': 'https://www.wikidata.org/wiki/Q186011', 'display_name': 'Stereochemistry', 'level': 1, 'score': 0.5909226}, {'id': 'https://openalex.org/C8010536', 'wikidata': 'https://www.wikidata.org/wiki/Q160398', 'display_name': 'Crystallography', 'level': 1, 'score': 0.35390824}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.15057787}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1021/om0494871', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S4924609', 'display_name': 'Organometallics', 'issn_l': '0276-7333', 'issn': ['0276-7333', '1520-6041'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320006', 'host_organization_name': 'American Chemical Society', 'host_organization_lineage': ['https://openalex.org/P4310320006'], 'host_organization_lineage_names': ['American Chemical Society'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': ['https://openalex.org/W4397444761', 'https://openalex.org/W4397487120', 'https://openalex.org/W4397350975'], 'versions': [], 'referenced_works_count': 20, 'referenced_works': ['https://openalex.org/W1542490233', 'https://openalex.org/W1950683812', 'https://openalex.org/W1969243791', 'https://openalex.org/W1991122220', 'https://openalex.org/W2000079595', 'https://openalex.org/W2000249116', 'https://openalex.org/W2005421416', 'https://openalex.org/W2007755556', 'https://openalex.org/W2010863884', 'https://openalex.org/W2012435897', 'https://openalex.org/W2018316419', 'https://openalex.org/W2028075563', 'https://openalex.org/W2064661036', 'https://openalex.org/W2075466219', 'https://openalex.org/W2085377744', 'https://openalex.org/W2139881842', 'https://openalex.org/W2140062566', 'https://openalex.org/W2142638355', 'https://openalex.org/W2168564681', 'https://openalex.org/W2952359107'], 'related_works': ['https://openalex.org/W2952982345', 'https://openalex.org/W2950665782', 'https://openalex.org/W2061950648', 'https://openalex.org/W2056162683', 'https://openalex.org/W2046352977', 'https://openalex.org/W2035229018', 'https://openalex.org/W1997177449', 'https://openalex.org/W1971156762', 'https://openalex.org/W1558598029', 'https://openalex.org/W1556952675'], 'abstract_inverted_index': {'The': [0, 17, 47], 'crystal': [1, 75, 83], 'structures': [2, 76], 'of': [3, 34, 43, 66, 73, 85], 'aggregates': [4], 'between': [5, 89], 'MeLi': [6, 18, 90], 'and': [7, 9, 77, 91], 'PhLi': [8, 27], 'a': [10, 22, 31, 35, 78], '(+)-sparteine': [11], 'surrogate': [12], '((+)-2)': [13], 'have': [14], 'been': [15, 94], 'determined.': [16], 'adduct': [19, 28], '4': [20], 'reveals': [21], '2:2': [23], 'dimer,': [24], 'while': [25], 'the': [26, 44, 63, 71, 74, 82, 86], '6': [29], 'forms': [30], 'rare': [32], 'example': [33], '4:2': [36], 'ladder': [37], 'structure,': [38], 'each': [39], 'capped': [40], 'by': [41], 'two': [42], 'diamine': [45], 'ligands.': [46], 'observation': [48], 'that': [49], '(+)-2': [50], 'is': [51, 68], 'equally': [52], 'effective': [53], 'as': [54], '(−)-sparteine': [55, 92], 'in': [56], 's-BuLi-mediated': [57], 'asymmetric': [58], 'deprotonations,': [59], 'but': [60], 'leading': [61], 'to': [62], 'opposite': [64], 'sense': [65], 'stereoselectivity,': [67], 'explained': [69], 'on': [70], 'basis': [72], 'computational': [79], 'study.': [80], 'Moreover,': [81], 'structure': [84], '2;2': [87], 'dimer': [88], 'has': [93], 'redetermined': [95], 'with': [96], 'advanced': [97], 'accuracy.': [98]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2061950648', 'counts_by_year': [{'year': 2022, 'cited_by_count': 1}, {'year': 2020, 'cited_by_count': 3}, {'year': 2019, 'cited_by_count': 3}, {'year': 2017, 'cited_by_count': 3}, {'year': 2016, 'cited_by_count': 1}, {'year': 2014, 'cited_by_count': 5}, {'year': 2013, 'cited_by_count': 5}, {'year': 2012, 'cited_by_count': 2}], 'updated_date': '2025-01-06T01:13:45.028276', 'created_date': '2016-06-24'}
Publication Information

Basic Information

Access and Citation

AI Researcher Chatbot

Primary Location

Authors

Topics

Keywords

Related Works
