Title: Adducts of thiophosphoryl compounds with metal halides. I.: Addition compounds of triphenylphosphine sulfide
Abstract: Abstract Addition compounds have been prepared of triphenylphosphine sulfide with HgCl 2 , AlCl 3 , AlBr 3 , SnCl 4 , TiCl 4 , TiBr 4 , SbCl 5 , NbCl 5 , TaCl 5 , FeCl 3 and FeCl 2 , and of triphenylphosphine oxide with AlCl 3 , AlBr 3 , TiBr 4 , SbCl 5 and TaCl 5 . Reaction of NbCl 5 with triphenylphosphine oxide yields the addition compound (Ph 3 PO) 2 NbOCl 3 . The syntheses, infrared spectra and some properties of the adducts are described and discussed.
Publication Year: 1966
Publication Date: 1966-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 24
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