Title: Vibrational spectroscopy at high pressures. Part 41.—Infrared spectra of acrylonitrile and polyacrylonitrile
Abstract: Acrylonitrile has been examined visually and by i.r. spectroscopy to 50 kbar. The liquid freezes at ca. 11 kbar. There is a phase transformation in the solid near 27 kbar. Above 10 kbar polyacrylonitrile co-exists with the liquid or solid phases: this polymer has an i.r. spectrum closely similar to that from the product of u.v.-induced polymerisation under ambient conditions.
Publication Year: 1982
Publication Date: 1982-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 1
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