Title: Addition compounds of dichlorodioxomolybdenum(VI) with sulfoxides. Molecular structure of [MoO2Cl2(Me2SO)2]
Abstract: MoO2Cl2L2 (L=dimethyl sulfoxide (Me2SO), deuterated dimethyl sulfoxide (Me2SO-d6), di-n-buthyl sulfoxide (Bu2SO), tetramethylene sulfoxide (C4H8SO), dibenzyl sulfoxide (Bz2SO), diphenyl sulfoxide (Ph2SO), di-p-tolyl sulfoxide (p-Tol2SO), di-p-chloro-phenyl sulfoxide (p-Cl-Ph2SO) and methyl phenyl sulfoxide (MePhSO)) have been prepared by reacting a solution of MoO2Cl2(H2O)2 in diethyl ether with the respective ligand. The molecular structure of MoO2Cl2(Me2SO)2 has been established by X-ray diffraction analysis. The ability of representative complexes to work as oxotransfer catalysts has been tested.
Publication Year: 2003
Publication Date: 2003-04-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 50
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