Title: CATALYTIC ASYMMETRIC OXIDATION OF SULFIDES MEDIATED BY A SERIES OF NOVEL OXAZOLINES-TITANIUM COMPLEXES
Abstract: A series of chiral oxazoline-titanium complexes were found to be efficient catalysts for the enantioselective oxidation of sulfides. The reactivity and enantioselectivity were strongly influenced by the structure of the oxazolines. When (4S,5S)-4,5-dihydro-4,5-diphenyl-2-(2′-hydroxy-3′-tert-butylphenyl) oxazoline was used as ligand, the sulfoxide was obtained in 96%e.e.
Publication Year: 2001
Publication Date: 2001-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 7
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