Title: Investigation of the macromolecular stable free nitroxide radical
Abstract: Polystyrene containing t-butyl nitroxide groups was prepared via polymer-analogous reactions and characterized by ESR measurements. Polymerizations of MMA and styrene initiated by AIBN at 50° have been investigated in the presence of the polymeric radical samples. A definite inhibiting effect was observed without retardation of the polymerization of either monomer. A linear relationship was found between the concentration of the polymeric inhibitor and the inhibition period.
Publication Year: 1978
Publication Date: 1978-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 2
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