Title: An NMR Study of Outer-Sphere Interactions of BF<sub>4</sub><sup>−</sup>Anions with Paramagnetic Ions
Abstract: Abstract The significance and role of outer-sphere interactions for the chemistry of complex compounds and solutions have been discussed in the literature time and again.1,2 The existence of the complexes per se in solutions is determined not only by the interactions of the central ion with the near-by ligands, but also with the particles of the outer or secondary coordination sphere. Now, while “intra-sphere” complexes may be both labile and inert with respect to their kinetic behavior in solutions, outer-sphere compounds are predominantly labile. Inasmuch as the majority of outer-sphere compounds cannot be isolated from solutions, NMR-spectroscopy is essentially one of the most convenient methods for their study. Naturally, such investigations are complicated by an exchange of particles constituting associate compositions, and this exchange may be sufficiently rapid to present interest in itself. Key Words: outer-sphere associatesNMR spectrafluoroborates
Publication Year: 1972
Publication Date: 1972-01-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 2
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot