Title: Direct Metal–Metal Bonds Between High and Low Valent Complex Fragments: The Reaction of Metal Bases with the Metal Acids [Re(NR)<sub>3</sub>]<sup>+</sup> and [Mo(NR)<sub>2</sub>]<sup>2+</sup>
Abstract: Shortened metal–metal bonds caused by electrostatic attraction within the dipolar (metal δ+ – metal δ− ) structural unit were observed in the heterobi‐ and heterotrimetallic complexes of type 1 and 2 . These complexes were synthesized from the imido complexes [(N t Bu) 3 ReCl] or [(N t Bu) 2 MoCl 2 ] and the carbonyl metalates K[M]. [M] = CpMo(CO) 3 , CpW(CO) 3 , Mn(CO) 5 , CpFe(CO) 2 , Co(CO) 4 . equation image
Publication Year: 1994
Publication Date: 1994-03-31
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 21
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