Title: Enantioselective Allylic Thioetherification: The Effect of Phosphoric Acid Diester on Iridium‐Catalyzed Enantioconvergent Transformations
Abstract: Angewandte Chemie International EditionVolume 51, Issue 34 p. 8652-8655 Communication Enantioselective Allylic Thioetherification: The Effect of Phosphoric Acid Diester on Iridium-Catalyzed Enantioconvergent Transformations† Correction(s) for this article Corrigendum: Enantioselective Allylic Thioetherification: The Effect of Phosphoric Acid Diester on Iridium-Catalyzed Enantioconvergent Transformations Markus Roggen, Erick M. Carreira, Volume 53Issue 2Angewandte Chemie International Edition pages: 348-348 First Published online: December 11, 2013 Markus Roggen, Markus Roggen ETH Zürich, HCI H335, 8093 Zürich (Switzerland)Search for more papers by this authorProf. Dr. Erick M. Carreira, Corresponding Author Prof. Dr. Erick M. Carreira [email protected] ETH Zürich, HCI H335, 8093 Zürich (Switzerland)ETH Zürich, HCI H335, 8093 Zürich (Switzerland)Search for more papers by this author Markus Roggen, Markus Roggen ETH Zürich, HCI H335, 8093 Zürich (Switzerland)Search for more papers by this authorProf. Dr. Erick M. Carreira, Corresponding Author Prof. Dr. Erick M. Carreira [email protected] ETH Zürich, HCI H335, 8093 Zürich (Switzerland)ETH Zürich, HCI H335, 8093 Zürich (Switzerland)Search for more papers by this author First published: 25 July 2012 https://doi.org/10.1002/anie.201202092Citations: 98 † M.R. acknowledges the Stipendienfonds Schweizerische Chemische Industrie (SSCI) and the Swiss National Science Foundation. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract You'll take the high road and I'll take the low road: Enantioenriched allylic thioethers have been synthesized from chiral racemic allylic alcohols. The combination of an Ir–(P,alkene) complex and dibutyl phosphoric acid are required to attain high selectivities. Mechanistic studies uncover an enantioconvergent transformation in which substrate enantiomers react along different pathways to give the same product (see scheme; cod=1,5-cyclooctadiene). Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201202092_sm_miscellaneous_information.pdf2.4 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue34August 20, 2012Pages 8652-8655 RelatedInformation
Publication Year: 2012
Publication Date: 2012-07-25
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 111
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