Title: <sup>1</sup>H‐NMR study on the tautomer ratios between the hydrazone imine and diazenylenamine forms in 3‐(arylhydrazono)‐methyl‐2‐oxo‐1,2‐dihydroquinoxalines
Abstract: Abstract The o ‐substituted 3‐(arylhydrazono)methyl‐2‐oxo‐1,2‐dihydroquinoxalines 1a‐c and 2a , c were synthesized to investigate the tautomeric behavior between the hydrazone imine A and diazenylenamine B forms in a series of mixed dimethyl sulfoxide/trifluoroacetic acid media. The chemical shifts of the hydrazone NH, N 4 ‐H, hydrazone CH, and diazenyl CH protons for o‐, m‐ , and p ‐substituted 3‐(arylhydrazono)methyl‐2‐oxo‐1,2‐dihydroquinoxalines 1 and 2 synthesized so far are summarized in Tables 3 and 4, respectively, which are found to be useful for the specification of the proton signals due to the hydrazone imine form A (hydrazone NH, hydrazone CH) and diazenylenamine form B (N 4 ‐H, diazenyl CH).
Publication Year: 1996
Publication Date: 1996-03-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 10
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