Title: Derivatives of divalent germanium, tin and lead. III. Tin(II) dithiolates
Abstract: Tin(II) dithiolates, Sn[SR]2 (R = Me, C6H13, C7H15 CH2Ph, Ph, p-tolyl), and the tin((II)-sulphur heterocycles Sn.S.CH2.CH2S and Sn.S.C6H4Me.S, have been synthesised by the protolysis of the tin(II)-carbon bond by thiols. Tin-119m Mössbauer and infra-red spectra are reported, and the structures of the compounds discussed. 2-Thioethanol reacts similarly to give tin(II)di(2-thioethoxide) and not the expected heterocycle Sn.S.CH2CH2O.
Publication Year: 1973
Publication Date: 1973-01-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 25
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