Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation

Name: Work Video:
Duration: 3 min 30 s
Description: Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.
Durga Prasad Hari; Burkhard König
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