Title: FORMATION OF CARBONYL YLIDE BY THE INTRAMOLECULAR CARBENIC REACTION. DISROTATORY RING CLOSURE OF CARBONYL YLIDE TO EPOXIDE
Abstract: Abstract Copper acetylacetonate catalyzed decomposition of 8-methoxycarbonyl-1-α-diazoacetylnaphthalene in benzene solution gave 2-hydroxy-3-methoxyphenalenone and 2,3-dihydroxyphenalenone via thermally forbidden disrotatory ring closure of intermediate carbonyl ylide to epoxide and successive cleavage of the epoxide.
Publication Year: 1976
Publication Date: 1976-03-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 12
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot