Title: Stable Singlet Carbenes—Plentiful and Versatile
Abstract: Angewandte Chemie International EditionVolume 43, Issue 14 p. 1767-1769 Highlight Stable Singlet Carbenes—Plentiful and Versatile Wolfgang Kirmse Prof. Dr., Wolfgang Kirmse Prof. Dr. [email protected] Fakultät für Chemie, Ruhr-Universität, Universitätsstrasse 150, 44780 Bochum, Germany, Fax: (+49) 234-32-14353Search for more papers by this author Wolfgang Kirmse Prof. Dr., Wolfgang Kirmse Prof. Dr. [email protected] Fakultät für Chemie, Ruhr-Universität, Universitätsstrasse 150, 44780 Bochum, Germany, Fax: (+49) 234-32-14353Search for more papers by this author First published: 24 March 2004 https://doi.org/10.1002/anie.200301729Citations: 131Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Electron donation from substituents is the principal mechanism of stabilizing singlet carbenes. Two amino groups are optimal (A). With additional steric protection, one amino group is sufficient (B). The effect of phosphanyl groups is enhanced by an electron acceptor as the second substituent (C). References 1Reviews: 1a Carbene Chemistry (Ed.: ), Marcel Dekker, New York, 2002; 1b Carben(oide), Carbine (Ed.: ), Houben-Weyl, Vol. E19b, Thieme, Stuttgart, 1989; 1cC. Wentrup, Reactive Molecules, Wiley, New York, 1984, chap. 4; 1dR. A. Moss, M. Jones, Jr., Carbenes Vol. I, Wiley, New York, 1973, R. A. Moss, M. Jones, Jr., Carbenes Vol. II, Wiley, New York, 1975; 1eW. Kirmse, Carbene Chemistry, 2nd ed., Academic Press, New York, 1971. 2Reviews: 2aR. A. Moss in Carbene Chemistry (Ed.: ), Marcel Dekker, New York, 2002, pp. 57–101; 2bR. A. Moss, Acc. Chem. Res. 1989, 22, 15–21; 2cR. A. 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Bourissou, G. Bertrand, J. Am. Chem. Soc. 2002, 124, 11 834–11 835. 18K. Miqueu, E. Despagnet-Ayoub, P. W. Dyer, D. Bourissou, G. Bertrand, Chem. Eur. J. 2003, 9, 5858–5864. Citing Literature Volume43, Issue14March 26, 2004Pages 1767-1769 ReferencesRelatedInformation
Publication Year: 2004
Publication Date: 2004-03-24
Language: da
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 135
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