Title: SYNTHESIS OF OPTICALLY ACTIVE PENTACOORDINATE SILICATES AND CORRESPONDING ASYMMETRIC ALLYLATION OF ALDEHYDES
Abstract:Abstract The optically active silicates 3a–c and disilicates 5a–b were synthesized. The asymmetric allylation reactions of aldehydes with optically active pentacoordinate allylsilicates were carried o...Abstract The optically active silicates 3a–c and disilicates 5a–b were synthesized. The asymmetric allylation reactions of aldehydes with optically active pentacoordinate allylsilicates were carried out to give optically active homoallylic alcohols 7a–b with 7–25% ee.Read More
Publication Year: 1998
Publication Date: 1998-11-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 1
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