Title: The crystal and molecular structure of oxo-π-cyclopentadienylπ-diphenylacetylene-σ-phenyltungsten
Abstract: X-Ray studies indicate that the photochemical reaction of C5H5W(CO)3C6H5 with tolane results in the formation of oxo-π-cyclopentádienyl-π-diphenylacetylene-σ-phenyltungsten. The observed shortening of WC(acetylene), WC(σ-phenyl) and WO bond lengths seems to be caused by an increased back donation due to the electron deficiency of the complex investigated.
Publication Year: 1973
Publication Date: 1973-06-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 44
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