Title: Redox reaction in 1-ethyl-3-methylimidazolium–iron chlorides molten salt system for battery application
Abstract: The redox reaction between divalent and trivalent iron species in binary and ternary molten salt systems consisting of 1-ethyl-3-methylimidazolium chloride (EMICl) with iron chlorides, FeCl2 and FeCl3, was investigated as a candidate of the half-cell reactions of novel rechargeable redox batteries based on low temperature molten salt systems. A reversible one-electron redox reaction between divalent and trivalent iron species was observed on a platinum electrode in EMICl–FeCl2–FeCl3 system at 130 °C. The voltammetric data indicated that divalent and trivalent iron species were FeCl3− and FeCl4− complex anions, respectively. Combined with another proper redox couple, this molten salt system can be utilized in a rechargeable redox battery on account of its low melting temperature and reversible redox reaction.
Publication Year: 2002
Publication Date: 2002-07-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 42
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