Title: Metallocene-Catalyzed Polymerization of Methacrylates to Highly Syndiotactic Polymers at High Temperatures
Abstract:Cs-Ligated ansa-zirconocene bis- and mono(ester enolate) complexes incorporating the diphenylmethylidene−(cyclopentadienyl)(9-fluorenyl) ligand, upon activation with appropriate activators, are highly...Cs-Ligated ansa-zirconocene bis- and mono(ester enolate) complexes incorporating the diphenylmethylidene−(cyclopentadienyl)(9-fluorenyl) ligand, upon activation with appropriate activators, are highly active catalysts for the syndiospecific polymerization of MMA at ambient temperature, leading to the production of PMMA with high syndiotacticity (rrrr = 94%) and glass transition temperature (Tg = 139 °C).Read More
Publication Year: 2008
Publication Date: 2008-02-01
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
Access and Citation
Cited By Count: 37
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