Title: Unprecedented Coordination of 4,4′,5,5′-Tetramethyl-2,2′-biphosphinine Doubly Bridging over an Open Triosmium Core
Abstract: European Journal of Inorganic ChemistryVolume 2000, Issue 5 p. 843-845 Short Communication Unprecedented Coordination of 4,4′,5,5′-Tetramethyl-2,2′-biphosphinine Doubly Bridging over an Open Triosmium Core Maarten J. Bakker, Maarten J. Bakker Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorFrank W. Vergeer, Frank W. Vergeer Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorFrantišek Hartl, František Hartl [email protected] Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorKees Goubitz, Kees Goubitz Laboratorium voor Kristallografie, Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorJan Fraanje, Jan Fraanje Laboratorium voor Kristallografie, Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorPatrick Rosa, Patrick Rosa Laboratoire "Hétéroéléments et Coordination" CNRS UMR 7653, École Polytechnique, 91128 Palaiseau Cedex, FranceSearch for more papers by this authorPascal Le Floch, Pascal Le Floch Laboratoire "Hétéroéléments et Coordination" CNRS UMR 7653, École Polytechnique, 91128 Palaiseau Cedex, FranceSearch for more papers by this author Maarten J. Bakker, Maarten J. Bakker Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorFrank W. Vergeer, Frank W. Vergeer Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorFrantišek Hartl, František Hartl [email protected] Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorKees Goubitz, Kees Goubitz Laboratorium voor Kristallografie, Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorJan Fraanje, Jan Fraanje Laboratorium voor Kristallografie, Institute of Molecular Chemistry, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The NetherlandsSearch for more papers by this authorPatrick Rosa, Patrick Rosa Laboratoire "Hétéroéléments et Coordination" CNRS UMR 7653, École Polytechnique, 91128 Palaiseau Cedex, FranceSearch for more papers by this authorPascal Le Floch, Pascal Le Floch Laboratoire "Hétéroéléments et Coordination" CNRS UMR 7653, École Polytechnique, 91128 Palaiseau Cedex, FranceSearch for more papers by this author First published: 20 April 2000 https://doi.org/10.1002/(SICI)1099-0682(200005)2000:5<843::AID-EJIC843>3.0.CO;2-RCitations: 16AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract The crystal structure of the novel cluster [Os3(CO)10(4,4′,5,5′-tetramethyl-2,2′-biphosphinine)] reveals an unprecedented coordination mode of the biphosphinine ligand that occupies a doubly-bridging position spanning the open osmium triangle. The cluster is photostable, pointing to a localization of the lowest-energy electronic transition largely on the negatively charged biphosphinine ligand. Citing Literature Volume2000, Issue5May 2000Pages 843-845 RelatedInformation
Publication Year: 2000
Publication Date: 2000-05-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 17
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot