Rastertunnelmikroskopisch beobachteter Ausdruck von Chiralität durch achirale coadsorbierte Moleküle in chiralen Monoschichten

Name: Work Video:
Duration: 3 min 30 s
Steven De Feyter; Petrus C. M. Grim; Markus Rücker; Peter Vanoppen; Christian Meiners; Michel Sieffert; Suresh Valiyaveettil; Kläus Müllen; Frans C. De Schryver
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'Rondelez,': [821], '1995,': [825], '75,': [826], '457–460;': [827], '10.1103/PhysRevLett.75.457': [828], 'I.': [833], 'Weissbuch,': [834], 'Berfeld,': [836], 'Bouman,': [838], 'Kjaer,': [840], 'Als-nielsen,': [842], 'Lahav,': [844], 'Leisorowitz,': [846], 'Am.': [848], 'Soc.': [850], '1997,': [851, 918, 929], '119,': [852], '933–942.': [853], '10.1021/ja9613926': [854], '11': [859], 'Moessner,': [872, 909], '100,': [885], '19636–19641.': [886], '10.1021/jp962737+': [887], '12': [892], 'Gesquière,': [901], '109,': [919], '2713–2715;': [920], '10.1002/ange.19971092309': [921], '36,': [930], '2601–2603.': [931], '10.1002/anie.199726011': [932], '13': [937], 'Positiv': [938], 'ist': [939], 'definert': [940], 'als': [941, 1044], 'Drehung': [942], 'Normalen': [945], 'zur': [946, 1112], 'Orientierung': [947], 'organisierten': [949], 'Struktur': [950], 'im': [951, 988, 992], 'Uhrzeigersinn.': [952], 'Normale': [954], 'kann': [955], 'die': [957, 961, 1024, 1045, 1047, 1081, 1103], 'Graphitachse': [958], '(θ)': [959], 'oder': [960], 'Lamellenachse': [962, 1062, 1113], '(φ)': [963], 'bezogen': [964], 'werden': [965], '(Abb.': [966], '2).': [967], '14': [970], 'Unsere': [971], 'Schlußfolgerungen': [972], 'basieren': [973], 'etwa': [975], '50': [976], 'STM-Aufnahmen': [977], 'jedes': [979], 'Enantiomer.': [980], 'Keines': [981], 'erhaltenen': [983], 'STM-Bilder': [984], 'steht': [985], 'den': [987], 'Text': [989], 'ausgeführten': [990], 'Ergebnissen': [991], 'Widerspruch.': [993], '15': [996], 'Diese': [997, 1075], 'Verbindung': [998], 'bildet': [999], 'zwei': [1000, 1035], 'Typen': [1001], 'Monoschichtstrukturen.': [1003], 'Einige': [1004], 'sind': [1006, 1019, 1041, 1078], 'vollkommen': [1007], 'ungeordnet': [1008], 'enthalten': [1010], 'ringartige': [1011], 'Strukturen,': [1012], 'einzelne': [1013], 'kleine': [1014], 'Lamellen': [1015, 1021], 'usw.': [1016], 'Andere': [1017], 'aufgebaut,': [1022], 'aber': [1023], 'Lamellenbreite': [1025], '(20': [1026], '±': [1027, 1038, 1066], 'Å)': [1029, 1040], 'intralamellare': [1032], 'Abstand': [1033], 'zwischen': [1034, 1054], 'Kopfgruppen': [1036], '(8.4': [1037], '0.2': [1039], 'viel': [1042], 'kleiner': [1043], 'Werte,': [1046], 'ISA-Moleküle': [1049], 'erhalten': [1050], 'wurden.': [1051], 'Winkel': [1053], 'Längsrichtung': [1056], 'ausgerichteten': [1058], 'Alkoxyketten': [1059], 'beträgt': [1063], 'ca.': [1064], '43': [1065], '2°.': [1067], 'Es': [1068], 'keine': [1070], 'Coabscheidung': [1071], 'beobachtet.': [1074], 'großen': [1076], 'Abweichungen': [1077], 'vermutlich': [1079], 'Etherfunktion': [1082], 'Alkylkette': [1085], 'Fehlen': [1088], 'eines': [1089], 'stereogenen': [1090, 1097], 'Zentrums': [1091], 'zurückzuführen.': [1092], 'Bei': [1093], 'ISA': [1094], 'zwingen': [1095], 'diese': [1096], 'Zentren': [1098], 'wahrscheinlich': [1099], 'aufgrund': [1100], 'sterischer': [1101], 'Hinderung': [1102], 'Seitenketten': [1104], 'eine': [1106, 1111], 'gestreckte': [1107], 'Konformation': [1108], 'nahezu': [1114], 'senkrechte': [1115], 'Orientierung.': [1116], '16': [1119], 'Freudenberg,': [1121], 'Lwowski,': [1123], 'Justus': [1124], 'Liebigs': [1125], 'Ann.': [1126], '1955,': [1128], '594,': [1129], '76.': [1130], '10.1002/jlac.19555940109': [1131], '17': [1136], 'Hjalmarsson,': [1138], 'H.-E.': [1139], 'Högberg,': [1140], 'Acta': [1141], 'Scand.': [1143], 'Ser.': [1144], '1985,': [1146], '39,': [1147], '793.': [1148], '10.3891/acta.chem.scand.39b-0793': [1149], 'Web': [1150], 'Citing': [1154], 'Literature': [1155], 'Volume110,': [1156], 'Issue9May': [1157], '1998Pages': [1159], 'This': [1161], 'is': [1162], 'German': [1164], 'Chemie.': [1168], 'Note': [1169], 'articles': [1171], 'published': [1172], 'since': [1173], '1962:': [1174], 'Do': [1175], 'not': [1176], 'cite': [1177], 'alone.': [1180], 'Take': [1181], 'me': [1182], 'International': [1185], 'Edition': [1186], 'citable': [1189], 'page': [1190], 'numbers,': [1191], 'DOI,': [1192], 'citation': [1194], 'export.': 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