Title: The fluoro(perfluoroalkylnitrile)noble-gas(<scp>II</scp>) cations, R<sub>F</sub>CN–NgF<sup>+</sup>(Ng = Kr or Xe; R<sub>F</sub>= CF<sub>3</sub>, C<sub>2</sub>F<sub>5</sub>, n-C<sub>3</sub>F<sub>7</sub>), and the fluoro(trifluoro-s-triazine)xenon(<scp>II</scp>) cation, s-C<sub>3</sub>F<sub>3</sub>N<sub>2</sub>N–XeF<sup>+</sup>; novel noble gas–nitrogen bonds
Abstract: Three novel examples of Kr–N bonds derived from perfluoroalkylnitriles, the RFCN–KrF+ cations, and their xenon analogues RFCN–XeF+(RF= CF3, C2F5, n-C3F7), have been prepared and characterized in BrF5 solvent by 19F and 129Xe n.m.r. spectroscopy; the Xe–N bonded cation s-C3F3N2N–XeF+, synthesized as the AsF6– salt, is stable at room temperature and has been fully characterized by 129Xe and 19F n.m.r. and Raman spectroscopy.
Publication Year: 1988
Publication Date: 1988-01-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 32
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot