Abstract: Abstract Potassium tetrachloro(ethylenediamine)iridate(III) and cis-dichlorobis(ethylenediamine) iridium(III) chloride were obtained by the reaction of iridium(III) chloride and ethylenediamine in a weakly acid aqueous solution. The condition for the formation of each compound depends on the mole ratio of iridium to ethylenediamine and pH of the solution. Trans-dichlorobis(ethylenediamine)iridium(III)chloride was prepared from potassium tetrachloro(ethylenediamine)iridate(III) and ethylenediamine. The geometrical configurations of the two isomers were determined by infrared spectra, and checked by ultraviolet spectra.
Publication Year: 1966
Publication Date: 1966-11-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 20
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