Title: Near‐IR Absorption Spectra for the Buckminsterfullerene Anions: an Experimental and Theoretical Study
Abstract:can exist in a number of oxidation states including , , , and . We describe in this paper near‐IR absorption peaks which are unique to these four oxidation states. These peaks are observed upon one, t...can exist in a number of oxidation states including , , , and . We describe in this paper near‐IR absorption peaks which are unique to these four oxidation states. These peaks are observed upon one, two, three, and four electron electrochemical reductions of . We have rationalized the energies and intensities of these electronic absorptions based on modifications of the known molecular orbital diagram of . The near‐IR absorptions reported here should provide a clear and unambiguous route for determining the oxidation state of in solution.Read More
Publication Year: 1992
Publication Date: 1992-07-01
Language: en
Type: article
Indexed In: ['crossref']
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Cited By Count: 128
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