Title: β‐Mannosides from β‐Glucosides by Intramolecular Nucleophilic Substitution with Inversion of Configuration
Abstract: Angewandte Chemie International Edition in EnglishVolume 27, Issue 8 p. 1086-1087 Communication β-Mannosides from β-Glucosides by Intramolecular Nucleophilic Substitution with Inversion of Configuration† Prof. Dr. Horst Kunz, Corresponding Author Prof. Dr. Horst Kunz Institut für Organische Chemie der Universität, J.-J.-Becher-Weg 18–20, D-6500 Mainz (FRG)Institut für Organische Chemie der Universität, J.-J.-Becher-Weg 18–20, D-6500 Mainz (FRG)Search for more papers by this authorDipl.-Chem. Wolfgang Günther, Dipl.-Chem. Wolfgang Günther Institut für Organische Chemie der Universität, J.-J.-Becher-Weg 18–20, D-6500 Mainz (FRG)Search for more papers by this author Prof. Dr. Horst Kunz, Corresponding Author Prof. Dr. Horst Kunz Institut für Organische Chemie der Universität, J.-J.-Becher-Weg 18–20, D-6500 Mainz (FRG)Institut für Organische Chemie der Universität, J.-J.-Becher-Weg 18–20, D-6500 Mainz (FRG)Search for more papers by this authorDipl.-Chem. Wolfgang Günther, Dipl.-Chem. Wolfgang Günther Institut für Organische Chemie der Universität, J.-J.-Becher-Weg 18–20, D-6500 Mainz (FRG)Search for more papers by this author First published: August 1988 https://doi.org/10.1002/anie.198810861Citations: 60 † This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract The β-mannoside bond in the core region of N-glycoproteins is difficult to form. The epimerization at C-2 of β-glucosides, which is normally difficult to achieve, has now been accomplished by intramolecular nucleophilic attack of a carbamate substituent in the sense of neighboring-group assistance. It was possible in this way to prepare directly isomerically pure (protected) β-mannosides like 1 from menthol and cholesterol as well as β-mannosidic disaccharides. Citing Literature Volume27, Issue8August 1988Pages 1086-1087 RelatedInformation
Publication Year: 1988
Publication Date: 1988-08-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 62
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot