Title: Anomalous behavior in the two-step reduction of quinones in acetonitrile
Abstract: The electrochemical reduction of eight quinones, 9,10-anthraquinone (1), duroquinone (2), 2,6-di-tert-butyl-1,4-benzoquinone (3), 2,6-dimethoxy-1,4-benzoquinone (4), 9,10-phenanthrenequinone (5), tetrachloro-1,2-benzoquinone (6), tetrabromo-1,2-benzoquinone (7) and 3,5-di-tert-butyl-1,2-benzoquinone (8), have been studied in acetonitrile. In every case it was found that cyclic voltammograms differed in significant ways from those expected for simple stepwise reduction of the quinone to its radical anion and dianion. The various types of deviations for the eight quinones have been cataloged and some speculation is offered concerning their origins.
Publication Year: 2001
Publication Date: 2001-03-01
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 100
AI Researcher Chatbot
Get quick answers to your questions about the article from our AI researcher chatbot