Title: Selective Preparation of the [3,5‐<i>t</i>Bu<sub>2</sub>‐1,2,4‐C<sub>2</sub>P<sub>3</sub>]<sup>−</sup> Ion and Synthesis and Structure of the Cationic Species <i>nido</i>‐[3,5‐<i>t</i>Bu<sub>2</sub>‐1,2,4‐C<sub>2</sub>P<sub>3</sub>]<sup>+</sup>, Isoelectronic with [C<sub>5</sub>R<sub>5</sub>]<sup>+</sup>
Abstract: Angewandte Chemie International EditionVolume 42, Issue 24 p. 2778-2782 Communication Selective Preparation of the [3,5-tBu2-1,2,4-C2P3]− Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu2-1,2,4-C2P3]+, Isoelectronic with [C5R5]+† Jason M. Lynam Dr., Jason M. Lynam Dr. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorMay C. Copsey, May C. Copsey School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorMichael Green Prof., Michael Green Prof. [email protected] School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorJohn C. Jeffery Dr., John C. Jeffery Dr. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorJohn E. McGrady Dr., John E. McGrady Dr. Department of Chemistry, University of York, Heslington, York, YO10 5DD, UKSearch for more papers by this authorChristopher A. Russell Dr., Christopher A. Russell Dr. [email protected] School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorJohn M. Slattery, John M. Slattery School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorAnthony C. Swain Dr., Anthony C. Swain Dr. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this author Jason M. Lynam Dr., Jason M. Lynam Dr. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorMay C. Copsey, May C. Copsey School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorMichael Green Prof., Michael Green Prof. [email protected] School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorJohn C. Jeffery Dr., John C. Jeffery Dr. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorJohn E. McGrady Dr., John E. McGrady Dr. Department of Chemistry, University of York, Heslington, York, YO10 5DD, UKSearch for more papers by this authorChristopher A. Russell Dr., Christopher A. Russell Dr. [email protected] School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorJohn M. Slattery, John M. Slattery School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this authorAnthony C. Swain Dr., Anthony C. Swain Dr. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509Search for more papers by this author First published: 17 June 2003 https://doi.org/10.1002/anie.200351096Citations: 54 † We thank the Leverhulme Trust (Emeritus Research Fellowship for M.G.), the Royal Society (University Research Fellowship for C.A.R.), the Ramsay Memorial Fellowship Trust (Research Fellowship for J.M.L.), the University of Bristol (M.G., C.A.R., J.M.L.), and the EPSRC (A.C.S., M.C.C., J.M.S.) for financial support. We would also like to thank Dr. Simon Duckett (York) for helpful discussions concerning the interpretation of NMR spectra. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Building pyramids: The first P–C cluster, namely, the novel nido species 2, is readily prepared from 1 (•=CtBu), which is also an excellent precursor for the selective synthesis of the anion 3. 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Publication Year: 2003
Publication Date: 2003-06-17
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 56
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