Publication Information

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{'洗剤中のα-オレフィンスルホン酸ナトリウム(AOS),直鎖アルキルベンゼンスルホン酸ナトリウム(LAS),アルキル硫酸ナトリウム(AS)の定量分析法を赤外吸収スペクトル(IR)により検討した.スルホネート混合系と同様にスルホニルクロライド誘導体にすることによりIR分析を行なうことを試みたが,ASのようなサルフェートの場合は,スルホネートと同じ条件ではROSO2ClとRClの混合物ができ定量することができなかった.しかしながら,触媒に用いたジメチルホルムアミドをスルホネートの場合の3倍以上(1.5ml以上)加えることにより,AOS,LASの反応を妨げることなく,ASを定量的にRClにすることができた.それぞれのスルホニル誘導体は,524,640および655cm-1に特性吸収帯をもち,これらをkeybandとして検量線を作成したところ,良好な直線関係を得た.AS,AOS,LAS混合品を7試料つくり,それぞれについて定量したところ,計算値と実測値がよく一致しており,最小二乗法による標準偏差は,ASσ=0.87%,AOSσ=0.94%,LASσ=0.51%であった.': [0]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W201899968', 'counts_by_year': [], 'updated_date': '2024-12-12T12:14:11.438551', 'created_date': '2016-06-24'}