Title: Intramolecular dimer radical anions of [3n] cyclophanes: transannular distance dependent stabilization energy
Abstract:Intramolecular dimer radical anions of [3n]cyclophanes generated by gamma-ray irradiation in low-temperature glassy matrices showed an absorption band attributable to charge resonance around 936-1210 ...Intramolecular dimer radical anions of [3n]cyclophanes generated by gamma-ray irradiation in low-temperature glassy matrices showed an absorption band attributable to charge resonance around 936-1210 nm, from which the stabilization energy of the dimer radical anions were analyzed on the basis of pi-electron delocalization over two benzene rings and the damping factor (beta) was estimated to be 0.35 A(-1), which is smaller than that of the intramolecular dimer radical cation of [3n]cyclophanes, indicating a effective charge delocalization of the dimer radical anions.Read More
Publication Year: 2009
Publication Date: 2009-01-01
Language: en
Type: article
Indexed In: ['crossref', 'pubmed']
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Cited By Count: 22
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