Structural spectroscopic and conformational studies of H2Ru2Rh2(CO)11(PPh3)

Name: Structural spectroscopic and conformational studies of H2Ru2Rh2(CO)11(PPh3)
Uploaded: 1986-11-01
Description: The structure of H2Ru2Rh2(CO)11(PPh3) has been studied by X-ray crystallography and by NMR spectroscopy. The arrangement of the carbonyl and the hydride ligands is similar to that in H2Ru2Rh2(CO)12. The phosphine is equatorially coordinated to the same basal rhodium as the other edge-bridging hydride ligand. A position cis to the phosphine is sterically favourable for the bridging hydride.
J. Pursiainen; Tapani A. Pakkanen
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