Title: Analytical approach to the helium-atom ground state using correlated wavefunctions
Abstract:A realistic three-parameter correlated wavefunction is used to construct an exact analytical expression for the expectation value of the helium-atom Hamiltonian expressed in the interparticle coordina...A realistic three-parameter correlated wavefunction is used to construct an exact analytical expression for the expectation value of the helium-atom Hamiltonian expressed in the interparticle coordinates. The parameters determined variationally are found to satisfy the orbital and correlation cusp conditions to a fair degree of accuracy and yield a value for the ground-state energy which is in good agreement with the exact result.Read More
Publication Year: 1996
Publication Date: 1996-03-14
Language: en
Type: article
Indexed In: ['crossref']
Access and Citation
Cited By Count: 33
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