Get quick answers to your questions about the article from our AI researcher chatbot
{'id': 'https://openalex.org/W2008512988', 'doi': 'https://doi.org/10.1063/1.452318', 'title': 'Tridiagonal Fermi resonance structure in the vibrational spectrum of the CH chromophore in CHF3. II. Visible spectra', 'display_name': 'Tridiagonal Fermi resonance structure in the vibrational spectrum of the CH chromophore in CHF3. II. Visible spectra', 'publication_year': 1987, 'publication_date': '1987-01-15', 'ids': {'openalex': 'https://openalex.org/W2008512988', 'doi': 'https://doi.org/10.1063/1.452318', 'mag': '2008512988'}, 'language': 'en', 'primary_location': {'is_oa': False, 'landing_page_url': 'https://doi.org/10.1063/1.452318', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S77047749', 'display_name': 'The Journal of Chemical Physics', 'issn_l': '0021-9606', 'issn': ['0021-9606', '1089-7690', '1520-9032'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320257', 'host_organization_name': 'American Institute of Physics', 'host_organization_lineage': ['https://openalex.org/P4310320257'], 'host_organization_lineage_names': ['American Institute of Physics'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}, 'type': 'article', 'type_crossref': 'journal-article', 'indexed_in': ['crossref'], 'open_access': {'is_oa': False, 'oa_status': 'closed', 'oa_url': None, 'any_repository_has_fulltext': False}, 'authorships': [{'author_position': 'first', 'author': {'id': 'https://openalex.org/A5109641524', 'display_name': 'Jeffrey J. Segall', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I97018004', 'display_name': 'Stanford University', 'ror': 'https://ror.org/00f54p054', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I97018004']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'J. Segall', 'raw_affiliation_strings': ['Department of Chemistry, Stanford University, Stanford, California 94305'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Stanford University, Stanford, California 94305', 'institution_ids': ['https://openalex.org/I97018004']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5024513735', 'display_name': 'Richard N. Zare', 'orcid': 'https://orcid.org/0000-0001-5266-4253'}, 'institutions': [{'id': 'https://openalex.org/I97018004', 'display_name': 'Stanford University', 'ror': 'https://ror.org/00f54p054', 'country_code': 'US', 'type': 'education', 'lineage': ['https://openalex.org/I97018004']}], 'countries': ['US'], 'is_corresponding': False, 'raw_author_name': 'R. N. Zare', 'raw_affiliation_strings': ['Department of Chemistry, Stanford University, Stanford, California 94305'], 'affiliations': [{'raw_affiliation_string': 'Department of Chemistry, Stanford University, Stanford, California 94305', 'institution_ids': ['https://openalex.org/I97018004']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5112814620', 'display_name': 'H.-R. Dübal', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'H. R. Dübal', 'raw_affiliation_strings': ['Laboratorium für Physikalische Chemie der ETH Zürich (Zentrum), CH-8092 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Laboratorium für Physikalische Chemie der ETH Zürich (Zentrum), CH-8092 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}, {'author_position': 'middle', 'author': {'id': 'https://openalex.org/A5108079348', 'display_name': 'Marius Lewerenz', 'orcid': None}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'M. Lewerenz', 'raw_affiliation_strings': ['Laboratorium für Physikalische Chemie der ETH Zürich (Zentrum), CH-8092 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Laboratorium für Physikalische Chemie der ETH Zürich (Zentrum), CH-8092 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}, {'author_position': 'last', 'author': {'id': 'https://openalex.org/A5043072345', 'display_name': 'Martin Qüack', 'orcid': 'https://orcid.org/0000-0002-1351-8584'}, 'institutions': [{'id': 'https://openalex.org/I35440088', 'display_name': 'ETH Zurich', 'ror': 'https://ror.org/05a28rw58', 'country_code': 'CH', 'type': 'education', 'lineage': ['https://openalex.org/I2799323385', 'https://openalex.org/I35440088']}], 'countries': ['CH'], 'is_corresponding': False, 'raw_author_name': 'M. Quack', 'raw_affiliation_strings': ['Laboratorium für Physikalische Chemie der ETH Zürich (Zentrum), CH-8092 Zürich, Switzerland'], 'affiliations': [{'raw_affiliation_string': 'Laboratorium für Physikalische Chemie der ETH Zürich (Zentrum), CH-8092 Zürich, Switzerland', 'institution_ids': ['https://openalex.org/I35440088']}]}], 'institution_assertions': [], 'countries_distinct_count': 2, 'institutions_distinct_count': 2, 'corresponding_author_ids': [], 'corresponding_institution_ids': [], 'apc_list': {'value': 3500, 'currency': 'USD', 'value_usd': 3500, 'provenance': 'doaj'}, 'apc_paid': None, 'fwci': 8.369, 'has_fulltext': True, 'fulltext_origin': 'ngrams', 'cited_by_count': 148, 'citation_normalized_percentile': {'value': 0.961326, 'is_in_top_1_percent': False, 'is_in_top_10_percent': True}, 'cited_by_percentile_year': {'min': 97, 'max': 98}, 'biblio': {'volume': '86', 'issue': '2', 'first_page': '634', 'last_page': '646'}, 'is_retracted': False, 'is_paratext': False, 'primary_topic': {'id': 'https://openalex.org/T10002', 'display_name': 'Advanced Chemical Physics Studies', 'score': 0.9989, 'subfield': {'id': 'https://openalex.org/subfields/3107', 'display_name': 'Atomic and Molecular Physics, and Optics'}, 'field': {'id': 'https://openalex.org/fields/31', 'display_name': 'Physics and Astronomy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, 'topics': [{'id': 'https://openalex.org/T10002', 'display_name': 'Advanced Chemical Physics Studies', 'score': 0.9989, 'subfield': {'id': 'https://openalex.org/subfields/3107', 'display_name': 'Atomic and Molecular Physics, and Optics'}, 'field': {'id': 'https://openalex.org/fields/31', 'display_name': 'Physics and Astronomy'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T12967', 'display_name': 'Molecular Spectroscopy and Structure', 'score': 0.997, 'subfield': {'id': 'https://openalex.org/subfields/1607', 'display_name': 'Spectroscopy'}, 'field': {'id': 'https://openalex.org/fields/16', 'display_name': 'Chemistry'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}, {'id': 'https://openalex.org/T11320', 'display_name': 'Atmospheric Ozone and Climate', 'score': 0.996, 'subfield': {'id': 'https://openalex.org/subfields/1902', 'display_name': 'Atmospheric Science'}, 'field': {'id': 'https://openalex.org/fields/19', 'display_name': 'Earth and Planetary Sciences'}, 'domain': {'id': 'https://openalex.org/domains/3', 'display_name': 'Physical Sciences'}}], 'keywords': [{'id': 'https://openalex.org/keywords/overtone', 'display_name': 'Overtone', 'score': 0.969332}, {'id': 'https://openalex.org/keywords/fermi-resonance', 'display_name': 'Fermi resonance', 'score': 0.9531622}, {'id': 'https://openalex.org/keywords/hamiltonian', 'display_name': 'Hamiltonian (control theory)', 'score': 0.43744963}], 'concepts': [{'id': 'https://openalex.org/C38615331', 'wikidata': 'https://www.wikidata.org/wiki/Q261967', 'display_name': 'Overtone', 'level': 3, 'score': 0.969332}, {'id': 'https://openalex.org/C2776565987', 'wikidata': 'https://www.wikidata.org/wiki/Q763192', 'display_name': 'Fermi resonance', 'level': 3, 'score': 0.9531622}, {'id': 'https://openalex.org/C185592680', 'wikidata': 'https://www.wikidata.org/wiki/Q2329', 'display_name': 'Chemistry', 'level': 0, 'score': 0.6203784}, {'id': 'https://openalex.org/C4839761', 'wikidata': 'https://www.wikidata.org/wiki/Q212111', 'display_name': 'Spectral line', 'level': 2, 'score': 0.55971473}, {'id': 'https://openalex.org/C139210041', 'wikidata': 'https://www.wikidata.org/wiki/Q2145840', 'display_name': 'Resonance (particle physics)', 'level': 2, 'score': 0.5385841}, {'id': 'https://openalex.org/C167812310', 'wikidata': 'https://www.wikidata.org/wiki/Q3492913', 'display_name': 'Rotational–vibrational spectroscopy', 'level': 3, 'score': 0.5173747}, {'id': 'https://openalex.org/C173523689', 'wikidata': 'https://www.wikidata.org/wiki/Q215589', 'display_name': 'Dipole', 'level': 2, 'score': 0.47796747}, {'id': 'https://openalex.org/C186769553', 'wikidata': 'https://www.wikidata.org/wiki/Q726648', 'display_name': 'Fermi Gamma-ray Space Telescope', 'level': 2, 'score': 0.46813142}, {'id': 'https://openalex.org/C41999313', 'wikidata': 'https://www.wikidata.org/wiki/Q489328', 'display_name': 'Molecular physics', 'level': 1, 'score': 0.4459937}, {'id': 'https://openalex.org/C130787639', 'wikidata': 'https://www.wikidata.org/wiki/Q5645293', 'display_name': 'Hamiltonian (control theory)', 'level': 2, 'score': 0.43744963}, {'id': 'https://openalex.org/C158355884', 'wikidata': 'https://www.wikidata.org/wiki/Q11388', 'display_name': 'Infrared', 'level': 2, 'score': 0.41247168}, {'id': 'https://openalex.org/C184779094', 'wikidata': 'https://www.wikidata.org/wiki/Q26383', 'display_name': 'Atomic physics', 'level': 1, 'score': 0.397614}, {'id': 'https://openalex.org/C153642686', 'wikidata': 'https://www.wikidata.org/wiki/Q70906', 'display_name': 'Infrared spectroscopy', 'level': 2, 'score': 0.35042465}, {'id': 'https://openalex.org/C46141821', 'wikidata': 'https://www.wikidata.org/wiki/Q209402', 'display_name': 'Nuclear magnetic resonance', 'level': 1, 'score': 0.32833067}, {'id': 'https://openalex.org/C121332964', 'wikidata': 'https://www.wikidata.org/wiki/Q413', 'display_name': 'Physics', 'level': 0, 'score': 0.233726}, {'id': 'https://openalex.org/C26873012', 'wikidata': 'https://www.wikidata.org/wiki/Q214781', 'display_name': 'Condensed matter physics', 'level': 1, 'score': 0.16085714}, {'id': 'https://openalex.org/C120665830', 'wikidata': 'https://www.wikidata.org/wiki/Q14620', 'display_name': 'Optics', 'level': 1, 'score': 0.10146329}, {'id': 'https://openalex.org/C126255220', 'wikidata': 'https://www.wikidata.org/wiki/Q141495', 'display_name': 'Mathematical optimization', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C33923547', 'wikidata': 'https://www.wikidata.org/wiki/Q395', 'display_name': 'Mathematics', 'level': 0, 'score': 0.0}, {'id': 'https://openalex.org/C178790620', 'wikidata': 'https://www.wikidata.org/wiki/Q11351', 'display_name': 'Organic chemistry', 'level': 1, 'score': 0.0}, {'id': 'https://openalex.org/C1276947', 'wikidata': 'https://www.wikidata.org/wiki/Q333', 'display_name': 'Astronomy', 'level': 1, 'score': 0.0}], 'mesh': [], 'locations_count': 1, 'locations': [{'is_oa': False, 'landing_page_url': 'https://doi.org/10.1063/1.452318', 'pdf_url': None, 'source': {'id': 'https://openalex.org/S77047749', 'display_name': 'The Journal of Chemical Physics', 'issn_l': '0021-9606', 'issn': ['0021-9606', '1089-7690', '1520-9032'], 'is_oa': False, 'is_in_doaj': False, 'is_core': True, 'host_organization': 'https://openalex.org/P4310320257', 'host_organization_name': 'American Institute of Physics', 'host_organization_lineage': ['https://openalex.org/P4310320257'], 'host_organization_lineage_names': ['American Institute of Physics'], 'type': 'journal'}, 'license': None, 'license_id': None, 'version': None, 'is_accepted': False, 'is_published': False}], 'best_oa_location': None, 'sustainable_development_goals': [], 'grants': [], 'datasets': [], 'versions': [], 'referenced_works_count': 46, 'referenced_works': ['https://openalex.org/W1604344096', 'https://openalex.org/W1970037703', 'https://openalex.org/W1971271591', 'https://openalex.org/W1973952825', 'https://openalex.org/W1974903021', 'https://openalex.org/W1975517077', 'https://openalex.org/W1986866131', 'https://openalex.org/W1987728816', 'https://openalex.org/W1993425381', 'https://openalex.org/W1999705960', 'https://openalex.org/W2011925781', 'https://openalex.org/W2014490224', 'https://openalex.org/W2016185365', 'https://openalex.org/W2018076876', 'https://openalex.org/W2023093924', 'https://openalex.org/W2023416446', 'https://openalex.org/W2024476841', 'https://openalex.org/W2030749506', 'https://openalex.org/W2032372151', 'https://openalex.org/W2032558749', 'https://openalex.org/W2033195290', 'https://openalex.org/W2037409027', 'https://openalex.org/W2041156835', 'https://openalex.org/W2042651455', 'https://openalex.org/W2042792876', 'https://openalex.org/W2046002177', 'https://openalex.org/W2046414157', 'https://openalex.org/W2049214434', 'https://openalex.org/W2053578667', 'https://openalex.org/W2055495620', 'https://openalex.org/W2057791226', 'https://openalex.org/W2061432492', 'https://openalex.org/W2065894615', 'https://openalex.org/W2070157733', 'https://openalex.org/W2070566656', 'https://openalex.org/W2076969992', 'https://openalex.org/W2079100756', 'https://openalex.org/W2086438106', 'https://openalex.org/W2122786310', 'https://openalex.org/W2142797210', 'https://openalex.org/W2149955703', 'https://openalex.org/W2152689268', 'https://openalex.org/W2322148089', 'https://openalex.org/W2580901971', 'https://openalex.org/W2996070834', 'https://openalex.org/W3142498894'], 'related_works': ['https://openalex.org/W2233758855', 'https://openalex.org/W2126388756', 'https://openalex.org/W2081180493', 'https://openalex.org/W2066609192', 'https://openalex.org/W2051952834', 'https://openalex.org/W2027929869', 'https://openalex.org/W2019261388', 'https://openalex.org/W2008512988', 'https://openalex.org/W1974572160', 'https://openalex.org/W1963525456'], 'abstract_inverted_index': {'The': [0, 136, 154, 174], 'near': [1], 'IR': [2], 'and': [3, 51, 106, 117, 171, 180], 'visible': [4], 'vibrational': [5, 77, 169], 'absorption': [6], 'spectra': [7, 47], 'of': [8, 16, 55, 86, 95, 100, 147, 163], 'CHF3': [9], 'were': [10], 'recorded': [11], 'up': [12], 'to': [13, 33, 89, 122, 151, 160], 'wave': [14], 'numbers': [15], '17': [17], '500': [18], 'cm−1': [19], 'providing': [20], 'complete': [21], 'frequency': [22, 31], 'coverage,': [23], 'together': [24], 'with': [25, 65, 183], 'paper': [26], 'I,': [27], 'from': [28], 'the': [29, 34, 44, 56, 73, 84, 96, 101, 126, 161, 184], 'low': [30, 74], 'fundamentals': [32], 'N=6': [35], 'CH': [36], 'stretching–bending': [37], 'overtone': [38, 46, 104, 128, 175], 'multiplet.': [39], 'All': [40], 'strong': [41], 'bands': [42, 111, 129, 137], 'in': [43, 113, 158], 'high': [45, 127], 'could': [48], 'be': [49, 139], 'predicted': [50], 'assigned': [52, 91], 'by': [53, 141], 'means': [54], 'tridiagonal': [57], 'Fermi': [58, 78, 108], 'resonance': [59, 79, 109], 'Hamiltonian,': [60], 'including': [61], 'a': [62, 87], 'few': [63], 'combinations': [64], 'intense': [66], 'CF3': [67], 'stretching': [68], 'vibrations': [69], 'already': [70], 'observed': [71], 'for': [72, 115, 166], 'overtones.': [75], 'Improved': [76], 'constants': [80], 'are': [81, 156, 178], 'presented': [82], 'on': [83], 'basis': [85], 'fit': [88], '35': [90], 'bands.': [92], 'An': [93], 'analysis': [94], 'rotational': [97, 131], 'fine': [98, 132], 'structure': [99, 133], '2ν4': [102], '(E)': [103], 'component': [105, 110], 'several': [107], 'result': [112], 'values': [114], 'αb': [116], 'αs,': [118], 'which': [119], 'allow': [120], 'us': [121], 'determine': [123], 'Be.': [124], 'In': [125], 'no': [130], 'is': [134], 'observed.': [135], 'can': [138], 'understood': [140], 'introducing': [142], 'additional': [143], 'homogeneous': [144], 'rovibrational': [145], 'structures': [146], 'phenomenological': [148], 'widths': [149], 'Γ≊1': [150], '10': [152], 'cm−1.': [153], 'results': [155], 'discussed': [157], 'relation': [159], 'separation': [162], 'time': [164], 'scales': [165], 'mode': [167], 'selective': [168], 'redistribution': [170], 'further': [172], 'evolution.': [173], 'band': [176], 'strengths': [177], 'reported': [179], 'analyzed': [181], 'approximately': [182], 'empirical': [185], 'local': [186], 'Mecke': [187], 'dipole': [188], 'function.': [189]}, 'cited_by_api_url': 'https://api.openalex.org/works?filter=cites:W2008512988', 'counts_by_year': [{'year': 2023, 'cited_by_count': 1}, {'year': 2021, 'cited_by_count': 1}, {'year': 2019, 'cited_by_count': 1}, {'year': 2018, 'cited_by_count': 2}, {'year': 2017, 'cited_by_count': 1}, {'year': 2014, 'cited_by_count': 1}], 'updated_date': '2024-12-18T12:12:02.596981', 'created_date': '2016-06-24'}